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filingDate 1968-03-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_aa8b44b5142485c5f9148f1b725bd245
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publicationDate 1970-07-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CH-494248-A
titleOfInvention Process for the preparation of new ruthenium complexes
abstract Ru complexes of formula (I) R=beta-diketone group; L= a ligand different from R; and x, y and z= integers, such that x+y+z=3, x > 1, 2 > 1, and y can be O. Group R has the formula (II). The ligand L is acetonitrile, propionitrile, acrylonitrile, triphenylphosphine, triphenylansine, triphenylstibine, or pyridine. (I) are prepd. by reacting a tris (beta-dionato) -Ru with a carbonyl-providing cpd. e.g. methoxyethanol or diethylene glycol, at 20-200 deg.C. The reaction can be carried out in the presence of hydrated Ru oxide, or metallic Ru or dodecacarbonyl-trimthenium on an inert carrier. (I) are useful as catalysts, esp. for the (hydro) dimerisation of acrylonitrile.
priorityDate 1967-03-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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