http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CA-3097206-A1

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filingDate 2019-04-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_497b4f11311a7a17d7aaaa71329b86c9
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publicationDate 2019-10-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CA-3097206-A1
titleOfInvention Synthesis of zinc mof materials
abstract Method for making a Zn MOF of formula Zn2Ht2CL, where Ht is 1,2,4-triazolate or a combination of 1,2,4-triazolate and one or more other cycloazocarbyl compound, and CL is oxalate or a combination of oxalate and one or more chelating ligand other than oxalate. More specifically, the Zn MOF is Zn2Tz2Ox, where Tz is 1,2,4-triazolate and Ox is oxalate. The method includes reacting 2 molar equivalents of 1,2,4-triazole or the combination with cycloazocarbyl compound with 1 molar equivalent of oxalate or the combination with other chelating ligand and adding 2 molar equivalents of Zn2+ to form the Zn MOF. The solvent used can be a lower alcohol or a miscible mixture of water and a lower alcohol. One or both reaction steps are conducted at a temperature less than or equal to 120 °C and can be conducted at room temperature and ambient pressure.
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