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filingDate 2001-07-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2010-02-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2010-02-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CA-2418231-C
titleOfInvention Process for producing polytrimethylene terephthalate
abstract A process for the polymerization of polytrimethylene terephthalate by esterification of terephthalic acid or dimethylterephthalate with 1,3-propane diol, precondensation of the esterification product to produce a precondensation product, and polycondensation of the precondensation product to produce polytrimethylene terephthalate and, as a byproduct, the cyclic dimer of terephthalic acid or dimethyl terephthalate and 1,3-propane diol, comprising: (a) recovering the cyclic dimer from the polymerization, (b) reacting from 0.5 to 25 percent by weight of the cyclic dimer in 1,3-propane diol in the presence of from 0.1 to 10 percent by weight of the cyclic dimer of a basic catalyst for five minutes to 24 hours at 50 to 210 .ordm.C, (c) optionally neutralizing the basic catalyst in the reaction product of (b), and (d) recycling the reaction product into the polymerization process.
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