http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CA-2371835-C

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filingDate 2000-02-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2010-07-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b08a0e25bb3f6a45463502dd29650c0a
publicationDate 2010-07-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CA-2371835-C
titleOfInvention Stereorigid, bridged metallocene catalysts for polyolefin production
abstract Use of a metallocene catalyst component for the preparation of a polyolefin which comprises an isotactic or polyolefin syndiotactic/isotactic block polyolefin having a monomer length of up to C10, which component has the general formula: R"C p R1R2R3)(C p'R1'R2')MQZ wherein Cp is a cyclopentadienyl ring substituted with at least one substituent; C p' is a substituted fluorenyl ring; R" is a structural bridge imparting stereorigidity to the component; R1 is optionally a substituent on the cyclopentadienyl ring which is distal to the bridge, which distal substituent comprises a bulky group of the formula XR*3 in which X is chosen from Group IVA, and each R* is the same or different and chosen from hydrogen or hydrocarbyl of from 1 to 20 carbon atoms, R2 is optionally a substituent on the cyclopentadienyl ring which is proximal to the bridge and positioned non-vicinal to the distal substituent and is of the formula YR#3 in which Y is chosen from group IVA, and each R# is the same or different and chosen from hydrogen or hydrocarbyl of 1 to 7 carbon atoms, R3 is optionally a substituent on the cyclopentadienyl ring which is proximal to the bridge and is a hydrogen atom or is of the formula ZR$3, in which Z is chosen from group IVA, and each R$ is the same of different and chosen from hydrogen or hydrocarbyl of 1 to 7 carbon atoms, R1' and R2' are each independently substituent groups on the fluorenyl ring, one of which is a group of the formula AR'''3, in which A is chosen from Group IVA, and each R''' is independently hydrogen or a hydrocarbyl having 1 to 20 carbon atoms and the other is hydrogen or a second group of the formula AR'''3; M is a Group IVB transition metal or vanadium; and each Q is hydrocarbyl having I to 20 carbon atoms or is a halogen.
priorityDate 1999-02-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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