http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CA-2274489-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_0efa077d881a96aeb1e29b21ef1bbb58 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-39 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-38 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C47-127 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-38 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-39 |
filingDate | 1997-12-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5a4857d4bb7a2efa6ff3e1c084d50685 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d3d97bfb3af75d8dd34ce6edab6d991e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b64ef591295790ea64f830f5820e5e7f http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ee954085211f14fbff82a82c40857f8a http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6d910e399b1dcc497693ba70681685dd http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1b1209662e762ae8ba39a17c209223ac http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9a8699b2f0ca84423210cf1225f1ecdd |
publicationDate | 1998-07-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CA-2274489-A1 |
titleOfInvention | Method for producing carbonyl compounds |
abstract | The invention relates to a method for producing carbonyl compounds of formula (I), in which R1 is a hydrogen atom or alkyl radical with between 1 and 3 C atoms; R2 is a hydrogen atom or a radical of formula (II), in which R3 is a hydrogen atom or, together with R4, an oxygen atom; R4 is the radical OR6 or, together with R3, an oxygen atom; R5 is a hydrogen atom, an alkyl radical with between 1 and 8 C atoms or a cyclohexyl or cyclopentyl radical; and R6 is an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CHO or -CH2-CH2-O-CH2-CHO. According to said method, the carbonyl compounds are produced by gas phase oxidation of methanol or alcohols of formula (III), in which R1 and R5 have the meaning assigned above and R7 is a hydrogen atom or an OR8 radical, and R8 is a hydrogen atom, an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH2-CH2-OH or -CH2-CH2-O-CH2-CH2-OH, with a gas containing oxygen, in the presence of catalysts containing copper and/or silver, and a phosphorus compound which is volatile under reaction conditions in such a quantity that the amount of phosphorus (calculated as P), in relation to the part by weight of alcohol used, is up to 20 ppm. Said method is characterized in that the quantity of phosphorus is added in at least two parts: a) the first part is added with the gaseous starting mixture before the catalyst bed, and b) at least one other part is added in the catalyst bed. |
priorityDate | 1996-12-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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