http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CA-2260891-C
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_91e5a84476c0d96ec09e1ea579d32439 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F110-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F10-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F297-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-645 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-64 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-60 |
filingDate | 1997-07-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2005-12-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3f215d9739e14b9274a49168456c8ad4 |
publicationDate | 2005-12-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CA-2260891-C |
titleOfInvention | Syndiotactic/atactic block polyolefins, catalysts and processes for producing the same |
abstract | Metallocene catalysts useful for the preparation of syndiotactic/atactic block polyolefins have the general formula: R"(C4R'mC5C4R'n) XMeQ wherein X is a hetero-atom ligand with one or two lone pair electrons selected from the elements of Group VA or VIA which can be substituted or non-substituted; (C4Rm'C5C4R'n') is a fluorenyl or a symmetrically substituted fluorenyl or cyclopentadienyl ring; R' is hydrogen or hydrocarbyl radical having from 1-20 carbon atoms, a halogen, an alkoxy, and alkoxy alkyl or an alkylamino or alkylsilylo radical, each R' may be the same or different and m and n independently are 0, 1, 2, 3 or 4, with the proviso that the bilateraly symmetry is maintained; R" is a structural bridge between X and the (C4R'mC5C4R'n) ring to impart stereorigidity; Q is a hydrocarbyl radical having 1-20 carbon atoms or is a halogen; Me is a Group IIIB, IVB, VB, or VIB metal as positioned in the Periodic Table of Elements; and Me can be in any of its theoretically possible oxidation states. Olefin monomers (particularly propylene) polymerised using those catalysts to form syndiotactic/atactic block polymers of high molecular weight and comprising at least 70 % of syndiotactic triads. |
priorityDate | 1996-07-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 70.