| abstract |
A polymer dispersant useful for improving the fluidity of cementitious compositions comprises a substituted polyimide or polyamide backbone, having at least some proportion of oligomeric or polymeric grafted side chains including one of amides, esters, and thioesters, having the general formula: wherein X is at least one of hydrogen, an alkali earth metal ion, an alkaline earth metal ion, ammonium ion, and amine; R is at least one of C1 to C6 alkyl(ene) ether and mixtures thereof and C1 to C6 alkyl(ene) imine and mixtures thereof; Q is at least one of oxygen, nitrogen, and sulfur; p is a number from 1 to about 300 resulting in at least one of a linear and branched side chain; R1 is at least one of hydrogen, C 1 to Co hydrocarbon, and functionalized hydrocarbon containing at least one of -OH, -COOH, a derivative of -COOH, sulfonic acid, a derivative of sulfonic acid, amine, and epoxy; Y is a hydrophobic hydrocarbon or polyalkylene oxide moiety that functions as a defoamer; m, m', m" , n, n', and n" are each independently 0 or an integer between 1 and about 20; Z is a moiety containing at least one of i) a compound containing at least one amine and one acid group, ii) two functional groups capable of incorporating into the backbone selected from the group consisting of dianhydrides, dialdehydes, and di-acid chlorides, and iii) a succinimide residue; and wherein a, b, c and d reflect the mole fraction of each unit wherein the sum of a, b, c and d equal one, wherein a, b, c and d are each a decimal of value greater than or equal to zero and less than one, and at least two of a, b, c and d are greater than zero. |