http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CA-2240612-A1
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_c72d118f5664072de841f9c5c34b9d99 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_b98e45aa4840d6d06ce1ee34fbb81d13 |
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-52 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2229-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2229-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2229-26 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C37-60 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J29-40 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C39-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C37-60 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C39-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C39-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C39-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J29-40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C39-27 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C39-08 |
| filingDate | 1998-06-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d75683c7368bf8e0004cac3380dc98a8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_33f39e48ca02b5b1acb783d0c158b082 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d5a85cd6099f9ea36b573041e84bf181 |
| publicationDate | 1999-01-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CA-2240612-A1 |
| titleOfInvention | Preparation of phenol and its derivatives |
| abstract | A method and a catalyst are described for selective oxidation of aromatic compounds (e.g., benzene and its derivatives) into hydroxylated aromatic compounds (e.g., corresponding phenols). For example, benzene can be converted into phenol with a yield of at least 30-40%, and a selectivity on the basis of benzene of at least 95-97%. The selectivity for this reaction based on N2O is at least 90-95%. Therefore, no substantial N2O decomposition or consumption for complete benzene oxidation to CO+CO2 or other side products occurs. Similar results are obtained with benzene derivatives (e.g., fluorobenzene, difluorobenzene, phenol), although the selectivity is somewhat lower in the case of derivatives (e.g., about 80-85% in the case of fluorosubstituted benzenes). A preferred catalyst for this process is a composition containing a high-silica pentasil-type zeolite (e.g, an HZSM-5 type zeolite) which contains no purposefully introduced additives such as transition or noble metals. The catalytic effect is achieved by performing a specific zeolite modification with strong Lewis acid-base centers of a specific nature. This modification can be achieved by a pretreatment comprising two steps: a first conventional calcination step at 300-600 °C, and a second high-temperature calcination step at 600 - 950°C. |
| priorityDate | 1997-07-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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