http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CA-2235812-A1

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C11-02
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C31-125
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-09
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C2-88
filingDate 1996-11-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8f3579e59daff012a2bcca21030cfbe7
publicationDate 1997-05-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CA-2235812-A1
titleOfInvention Coproduction of vinylidene alcohols and vinylidene hydrocarbons
abstract A process is described for coproducing vinylidene alcohol and vinylidene olefin. The process involves dimerizing one or more vinylolefins with an alkyl aluminum catalyst to form a first product mixture comprising at least vinylidene olefin and alkyl aluminium compound. The vinylidene olefin is then reacted with the alkyl aluminium compound under displacement conditions to form 1-olefin while concurrently removing the 1-olefin from the displacement reaction mixture to form a second product mixture comprising at least beta-branched alkyl aluminum compound. The second product mixture is treated with air or oxygen under mild oxidation conditions to form a third product mixture comprising at least beta-branched aluminum alkoxide. The beta-branched aluminum alkoxide is then hydrolyzed to form vinylidene alcohol. The process makes effective use of the alkyl aluminum catalyst both as a catalyst and as a reactant, and requires only a relatively small amount of reaction equipment.
priorityDate 1995-11-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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