http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CA-2228801-A1
Outgoing Links
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| filingDate | 1998-02-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_114d70a4781eedc12ca5a188e5419196 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6a4c53938061015789f2d9958ab050d8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f9816a4cfe2bdb7ec76c74cf8c65ff59 |
| publicationDate | 1999-08-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CA-2228801-A1 |
| titleOfInvention | New ionic materials for use as electrolyte solutions |
| abstract | Compounds forming salts M + X- corresponding to the general formula next: in which: ~ M + represents: the cation H +, a hydroxonium, a cation metallic with valence n (Li +, Na +, K +, Rb +, Cs +, Mg2 +, Ca2 +, Cu2 +, Zn2 +, Sn2 +, Sm2 +, Sm3 +, La3 +, Ho3 +, Sc3 +, Al3 +, Y3 +, Yb3 +, Lu3 +, Eu3 +, ...), an opium (R2 jO + (oxonium), NR4 + (ammonium), RC (NH 2-j R j) 2+ (amidinium), C (NH 2-j R j) 3+ (guanidinium), R j C5H 6-j N + (pyridinium), R j C3H 5-j N2 + (imidazolium), R j H 5-j N2 + (sulfamidium), NO + (nitrosyl), NO2 + (nitronium), SR3 + (sulfonium), PR4 + (phosphonium), IR2 + (iodonium), (R j C 6H 4-j) 3C + (trityle) ...), or an organo-metallic complex cationic, as well as organic polycations or organo-metallic ... R j independently represents a radical: H, alkyl, alkenyl, oxa-alkyl, oxa-alkenyl, aza-alkyl, aza-alkenyl, thia-alkyl, thia-alkenyl, aryl, alkylaryl, alkenylaryl, cyclic, heterocyclic ..., as well as their derivatives substitution in the side chains and / or the aromatic part by heteroatoms such as nitrogen, oxygen, sulfur ... these radicals can be simple, halogenated or perhalogenated, j being between 1 and at most 5 in the examples cited; ~ XF represents: -a mono or polyvalent perhalogenated radical: alkyl, alkenyl, oxa-alkyl, oxa-alkenyl, aza-alkyl, aza-alkenyl, thia-alkyl, thia-alkenyl, aryl, alkylaryl, arylalkyl, alkenylaryl, cyclic, heterocyclic, as well as their derivatives of substitution in the side chains and / or the aromatic part by heteroatoms such as nitrogen, oxygen, sulfur ... which may contain oxa, aza or thia substituents, a radical R x CF2 ~, R x CF2CF2 ~, R x CF2CF (CF3) ~, CF3C (R x) F ~ R x representing a radical: H, alkyl, alkenyl, oxa-alkyl, oxa-alkenyl, aza-alkyl, aza-alkenyl, thia-alkyl, thia-alkenyl, aryl, alkylaryl, alkenylaryl, cyclic, heterocyclic ..., as well as their substitution derivatives in chains side and / or the aromatic part by heteroatoms such as nitrogen, oxygen, sulfur ... these radicals can be simple or partially halogenated halogenated and by extension versatile for example ~ CF2R x CF2 ~. -an all or part alkoxy radical substituted by perfluorinated groups such as: CF3CH2O-, (CF3) 2CHO-, (CF3) 3COH-, -OCH2 (CF2) n CH2O-(1 <n <20), -a fluorine atom, ~ x is 1 or 2 ~ Y represents: a) a carbonyl, sulfonyl, thionyl group or phosphonyl, R then represents a mono or polyvalent radical: -alkyl, alkenyl, oxa-alkyl, oxa-alkenyl, aza-alkyl, aza-alkenyl, thia-alkyl, thia-alkenyl, cyclic, ... as well as their substitution derivatives in the side chains by heteroatoms such that nitrogen, oxygen, sulfur ... these radicals can be halogenated if x = 1 or if x = 2 when R is an all or part alkoxy radical substituted by perfluorinated groups such as: CF3CH2O-, (CF3) 2CHO-, (CF3) 3COH-, -OCH2 (CF2) n CH2O-(1 <n <20), CF3O-, CF2 = CFO -, ... -aryl, alkylaryl, alkenylaryl, heterocyclic, alkylheterocyclic, alkenylheterocyclic ... These radicals can be simple or halogenated, -R2N, the radicals R being alkyl, alkenyl, oxa-alkyl, oxa-alkenyl, aza-alkyl, aza-alkenyl, thia-alkyl, thia-alkenyl, aryl, alkylaryl, alkenylaryl, cyclic, heterocyclic ..., as well as their substitution derivatives in chains side and / or the aromatic part by heteroatoms such as nitrogen, oxygen, sulfur ... these radicals can be simple or halogenated and by extension versatile, -a fluorine atom, - radicals allowing the anion to be introduced into a polymer frame: (Ry) 3-j CH j CF2- (Ry) 3-j CH j CF2CF2- (Ry) 3-j CH j (CF2) n (CF2) 3-n being between 0 and 20, j being between 0 and 2, the Ry (s) independently represent a non-halogenated group allowing homopolymerize or copolymerize the anion by various processes: anionic, cationic, radical, polycondensation, telomerization, ... and containing for example at least: a maleimide substituted or unsubstituted, a vinyl ether, a propenyl ether, an acrylate, an allyl, a vinyl, a styrene, a epoxy, methylstyrene, vinylsulfone, dioxolane, an alcoholate, a carboxylate, a amine, aldehyde, isocyanate, halogen, ... - radicals: (R y) 3-j CH j CF2- (R y) 3-j CH j CF2CF2-I (R y) 3-j CH j (CF2) n (CF2) 3-n being between 0 and 20, the Ry independently represent a group not halogenated, j being between 0 and 2, Ry represent a non-halogenated alkyl group, aryl, alkylaryl, ... b) if Y represents nothing, then denote the radical RY by Z, Z represents an electron-withdrawing radical monovalent: -a pseudo-halogen: NO2, SCN, N3, CN, OCF3, OC n F2n + 1, OC2F4H, OCF = CF2, CF3, SCF3, SC n F2n + 1, SC2F4H, ... -a radical whose defined electron-withdrawing power by the parameter of Hammett s * is higher or equal to the value determined for phenyl either s *> 0.6, ~ Q represents a radical -N-- or -C - (Y'-R '), when Q is -N--, RY can represent a radical R x CF2 ~, R x CF2CF2 ~, R x CF2CF (CF3) ~, CF3C (R x) F ~ R x representing a radical: H, alkyl, alkenyl, oxa-alkyl, oxa-alkenyl, aza-alkyl, aza-alkenyl, thia-alkyl, thia-alkenyl, aryl, alkylaryl, alkenylaryl, cyclic, heterocyclic ..., as well as their substitution derivatives in chains side and / or the aromatic part by heteroatoms such as nitrogen, oxygen, sulfur ... these radicals can be simple or partially halogenated halogenated and by extension versatile for example ~ CF2R x CF2 ~, ~ Y'-R'represent: -a radical YR as defined above, -a hydrogen atom. ~ RY or R'-Y 'or XFS (O) x- can be joined to form a cycle any. |
| priorityDate | 1998-02-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
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Total number of triples: 227.