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filingDate 1996-02-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_64cd39671670937a256d649587f8db33
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publicationDate 1996-09-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CA-2170705-A1
titleOfInvention Process for the preparation of ¹-caprolactam
abstract Process for the preparation of .epsilon.-caprolactam starting from 5-formylvalerate acid, ester or amide (aldehyde compound) in which a reaction in the presence of ammonia and hydrogen and a subsequent cyclization of the reaction products thus formed (.epsilon.-caprolactam-precursors) to .epsilon.-caprolactam is performed in the presence of water, wherein that the following steps are performed (a) contacting the 5-formylvalerate acid, ester or amide with ammonia and water under non-hydrogenation conditions, (b) contacting the resulting mixture of step (a) with hydrogen in the presence of ammonia under hydrogenation conditions, in which the water content is higher than 10 wt.%, (c) heating the resulting mixture of step (b) at a temperature between 200 and 350°C in order to convert the reaction products of step (b) to .epsilon.-caprolactam.
priorityDate 1995-03-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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