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filingDate 1992-09-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2006-07-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6404a48966178523b0d016cdb08b3bf8
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publicationDate 2006-07-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CA-2119738-C
titleOfInvention Control of a solution process for polymerization of ethylene
abstract A solution process for the preparation of high molecular weight polymers of alpha-olefins selected from the group consisting of homopolymers of ethylene and copolymers of ethylene and C3-C12 higher alpha-olefins is disclosed. Ethylene and/or mixtures of ethylene and C3-C12 higher alpha-olefins are polymerized under non-isothermal conditions in a tubular reactor or in a system of reactors which operate under different conditions, in the presence of a catalytic amount of a titanium-containing coordination catalyst in an inert solvent at a temperature in excess of 105°C. The improvement is characterized in that: (a) the catalyst is activated with a solution of a mixture of aluminum alkyl and alkoxy aluminum alkyl in inert solvent; and (b) the process is controlled by adjusting the ratio of aluminum alkyl to alkoxy aluminum alkyl in the mixture of (a). The aluminum alkyl is of the formula AlR n X3-n and the alkoxy aluminum alkyl is of the formula AlR' m OR"3-m. in which each of R, R' and R" is alkyl or aryl of 1-20 carbon atoms, X is halogen, n is 2-3 and m is 0-3.
priorityDate 1991-10-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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