http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CA-2081887-C

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filingDate 1991-04-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2001-08-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ef32b1078e6d4f3bbc806a14ad4f9109
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publicationDate 2001-08-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CA-2081887-C
titleOfInvention Solution process for the preparation of polymers of alpha-olefins
abstract A solution process, and a catalyst therefor, for the preparation of high molecular weight polymers of alpha-olefins viz. homopolymers of ethylene and copolymers of ethylene and C3-C12 alpha-olefins, is disclosed. The process is operated under solution polymerization conditions at 105-320°C. The catalyst is obtained from titanium tetrahalides, vanadium oxytriha-lides and organoaluminum compounds, in which an admixture of catalyst components is heat-treated at 180-250°C and subsequently cooled to a temperature of less than 150°C. Additional vanadium oxytrihalide is then added. The resultant ca-talyst solution is activated with an aluminum compound. The catalyst has good activity, showing superior activity to catal-ysts in which additional vanadium oxytrihalide is not added or added at temperatures above 150°C.
priorityDate 1990-05-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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