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filingDate 1992-08-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_aa0baad495ae12083cb0d62faa67b79a
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4bc11319277842957771be74dff32217
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publicationDate 1993-03-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CA-2076279-A1
titleOfInvention Superconductive layer on monocrystalline substrate and process for its preparation
abstract Abstract: A superconductive article is disclosed comprised of a substrate having a monocrystalline oxide surface supporting a superconductive crystalline oxide layer satisfying the formula: P2Sr2CanCUn+1O6+2n-z where P represents Bi1-zPbz; n is zero, 1 or 2; and z is 0 to 0.30. At least half of the crystal unit cells of the superconductive crystalline oxide layer are oriented with their c-axes normal to the substrate surface and with their minor axes relatively angularly aligned within a deviation range of less than 5°. The superconductive crystalline oxide layer is formed by (a) applying to the substrate surface a coating solution comprised of a volatilizable film forming solvent and metal-ligand compounds of each of P, Sr, Ca and Cu containing at least one thermally volatilizable organic ligand, with at least one fluoro-substituted organic compound providing a F:Sr atomic ratio of at least 3:1, (b) removing the volatile components of the coating by heating and (c) forming the residual components of the coating into the superconductive crystalline oxide layer by firing to a temperature in the range of from 800 to 860°C.
priorityDate 1991-09-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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