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publicationDate 1998-11-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CA-2023663-C
titleOfInvention Process of forming phospate coatings on metal surfaces
abstract A process of forming phosphate coatings on metal surfaces by a treatment with aqueous iron(II) and nitrate ions-containing zinc phosphate solutions can be carried out without a formation of waste water if metal surfaces are contacted with a phosphating solution which contains: 0.4 to 30 g/l Zn, 4 to 30 g/l P205, 5 to 50 g/l N03, from greater than 0 to 10 g/l Fe(II), and from greater than 0 to 0.3 g/l Fe(III) and in which the weight ratio of free P205 to total P2O5 = (0.04 to 0.50) : 1 and which is replenished with Zn, NO3 and P2O5 in a weight ratio of: Zn : NO3 : P205 = (0.80 to 0.30) : (0.17 to 0.4) : 1 and in which the Fe(II) content is adjusted only by an oxidation with nitrate or nitrite derived from nitrate, nitrite derived from nitrate, employed optionally together with an oxygen-containing gas, H202 and/or nitrous gases, the phosphating bath is succeeded by a cascade of at least two rinsing baths, low-salt water or salt-free water is fed to that rinsing bath which is the last in the direction of travel of the workpieces, the overflowing water is fed to the next preceding rinsing bath and to the phosphating bath, respectively, and low-salt or salt-free water is withdrawn from the phosphating bath at least at such a rate that the phosphate-enriched rinsing water form the cascade can be fed to the phosphating bath.
priorityDate 1989-08-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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