http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CA-1269396-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_d669af06cb2abbcd6823699582a97002 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C323-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C265-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C265-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C263-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C323-57 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C241-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J23-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J23-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C313-00 |
filingDate | 1986-03-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 1990-05-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e7160ec9230178813787e9007f17a45d http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e6e021a3c0e988950582c30f7e68e1e6 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7ec927dc7ec56b3dcde1429cee5ae466 |
publicationDate | 1990-05-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CA-1269396-A |
titleOfInvention | Process for producing 2-isocyanato-2,3-dehydro carboxylic esters |
abstract | ABSTRACT OF THE DISCLOSURE 2-isocyanato-2,3-dehydrocarboxylic acid esters having the general formula wherein R1 represents a straight-chain or branched (C1-C4)alkyl radical, a phenyl radical or a benzyl radical, and R2 represents hydrogen or a methyl radical and R3 represents a straight-chain or branched (C1-C16)alkyl radical, a (C3-C8)cycloalkyl radical, a (C1-C6)alkyl-mercapto radical or a phenyl radical, are pro-duced by reacting 2-azido-carboxylic acid esters having the general formula (II) in an inert solvent at a temperature of between 0 and 150°C in the presence of a perrhenate with phosgene or diphosgene. The compounds having the general formula (I) can be converted with benzyl alcohol or with tert-butyl alcohol into the correspond-ing 2- and BOC-protected 2,3-dehydro-2-aminocarboxylic acid esters, which are in turn valuable components for the synthesis of dehydro peptides. |
priorityDate | 1985-03-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 126.