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filingDate 1985-09-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1989-09-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d6672ae0150e155e70052dab6980ac19
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publicationDate 1989-09-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CA-1259447-A
titleOfInvention Method of catalyst deactivation
abstract ABSTRACT OF THE DISCLOSURE An improved method of terminating ethylene polymerization and interpolymerization reactions by deactivating the Ziegler-type catalyst used in the reaction comprises the step of injecting a selected deactivating agent into the molten polymer solution in the polymerization reactor prior to degassing of the polymer solution. The deactivating agent is selected from the group consisting of: (a) natural hydrotalcite minerals and synthetic hydrotalcite-like materials; b) Group IIIA metal salts of monocarboxylic acids; (c) alkali metal and alkaline earth metal salts of alkarylsulfonic acids; (d) alkali metal and alkaline earth metal salts of alkyl and alkaryl sulfuric acids; (e) organophosphites of a formula selected from the group consisting of (RO)3P and (RO)2POH where R is a hydrocarbon group containing 1 to 22 carbon atoms, inclusive; (f) ethoxylated hydrocarbylamines of the formula R'3_nN[(OCH2CH2)moH]n where R' is hydrogen or a hydrocarbon group containing 1 to 22 carbon atoms, inclusive, and at least one R' is a hydrocarbon group, n is 1 or 2, and m is an integer between 1 and 22, inclusive; (g) monocarboxylic acid esters of triethanolamine of the formula (RCOOCH2CH2)3N where R is a hydrocarbon group containing 1 to 22 carbon atoms, inclusive; and (h) organotin salts of maleic acid of the formula [-Sn(R)200CCH=CHCOO-] where R is a hydrocarbon group containing 1 to 22 carbon atoms, inclusive.
priorityDate 1985-01-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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