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filingDate 1982-02-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1984-09-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_00bffa30a0a5c5a7ffc0058ef7840410
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7a503c06c1df8515f9ea291230ffc989
publicationDate 1984-09-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CA-1174246-A
titleOfInvention Process for producing normal-octanol
abstract Abstract of the Disclosure A process for producing n-octanol which comprises the steps of (i) reacting butadiene with water in a solution containing water, a carbonate and/or bicarbonate salt of a monodentate tertiary amine having a basicity constant (pKa) of not less than 7, and sul??lane in the proportions of 25-55 percent, 5-30 percent and 30-65 percent by weight based on the reaction mixture, respectively, in the presence of a palladium compound and a hydrophilic monodentate phosphine in an amount of at least 6 moles per gram atom of palladium, to form 2,7-octadien-1-ol; (ii) extracting 2,7-octadien-1-ol from at least part of the reaction mixture obtained in step (i) with a saturated aliphatic hydro-carbon, a monoolefinic hydrocarbon or an alicyclic hydrocarbon, and recycling the extraction residue to the 2,7-octadien-1-ol synthesis step (i); (iii) subjecting the extract layer containing 2,7-octadien-1-ol as obtained in step (ii) to distillation at a liquid phase temperature of not higher than about 100°C to distill off a large proportion of the extracting solvent therefrom, followed by distillation in the presence of water, whereby the extructing solvent remaining is distilled of e in the form of an azeotropic mixture with water, to obtain a distillation residue: (iv) recovering 2,7-octadien-1-ol from the distillation residue obtained in step (iii) by distillation (v) hydrogenating the 2,7-octadien-1-ol obtained in step (iv) in the presence of a hydrogenation catalyst to obtain n-octanol; and (vi) recovering n-octanol from the hydrogenation reaction mixture by distillation.
priorityDate 1981-02-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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