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filingDate 2006-10-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_45a3a5e50319389b9eca3d7c94399192
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publicationDate 2019-02-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber BR-PI0618384-B1
titleOfInvention Boronide metallocene complex of a lanthanide, complex preparation and olefin copolymerization processes, and catalytic system
abstract boronide metallocene complex of a lanthanide, olefin complex copolymerization and complex preparation processes, catalytic system, and ethylene and butadiene copolymer. The present invention relates to a metallocene boroidride complex of a lanthanide, its preparation process, a catalytic system incorporating it, an olefin copolymerization process through this catalytic system and an ethylene / butadiene copolymer obtained by this process, whose butadiene units comprise 1,2-cyclohexane or 1,2 and 1,4-cyclohexane threads. A complex according to the invention responds to either of the following formulas <um> a <mv> and <um> b <mv> where, in formula <um> a <mv>, they are bound to lanthanide ln such as nd, two cp-1- and cp-2-ligand molecules, each consisting of a fluorenyl group and wherein, in the formula <um> b <mv> lanthanide is attached to a ligand molecule, consisting of two fluorenyl groups cp ~ 1 ~ and cp ~ 2 ~ which are linked together by a bridge p of formula mr ~ 1 ~ r ~ 2 ~, where m is an element of the iva column such as itself, where r ~ 1 ~ and r ~ 2 ~ identical or different, represent an alkyl group comprising from 1 to 20 carbon atoms, where l represents an alkali metal such as li, where n represents a molecule of a complexing solvent such as thf, where x is an integer or not greater than 0, and where p is an integer equal to or greater than 1.
priorityDate 2005-11-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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