http://rdf.ncbi.nlm.nih.gov/pubchem/patent/AR-121017-A1
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_ac6ccbfcd2a57629c9fbe8d48244de3d |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D239-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/A01P13-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D239-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/A01N43-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D409-10 |
| filingDate | 2021-01-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_41d8b81691988e5a51d943a8f43cfced http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c5f2609f63c4bab1e47fbf2a36d5db9f http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_76b3497d8cd8a3e4511eacdb391ba750 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_691854efba09a55059f5e2fb223d3a76 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_60f2bff28406f828c4653ac8f2f98a75 |
| publicationDate | 2022-04-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | AR-121017-A1 |
| titleOfInvention | SUBSTITUTED IMINOARYL COMPOUND WITH CARBOXYLIC ACID DERIVATIVE, PREPARATION METHOD, HERBICIDE COMPOSITION AND USE THEREOF |
| abstract | The present relates to the field of pesticide technology, and in particular, to a kind of carboxylic acid derivative substituted iminoaryl compound, preparation method, herbicidal composition and use thereof. The compound, as shown in the general formula (1) wherein Q represents, a compound of the group of formulas (2); Y represents halogen, haloalkyl or cyano; Z represents halogen; M represents CH or N; W represents OX⁵, SX⁵ or N(X⁵)₂; X represents -CX¹X²-(alkyl)ₙ-, -alkyl-CX¹X²-(alkyl)ₙ- or -(CH₂)ʳ-; X³ and X⁴ each independently represent O, S, NH or N-alkyl, etc. The compound has excellent herbicidal activity against gramineous weeds, broadleaf weeds, sedge weeds, etc. even at low application rates, and has high crop selectivity. Claim 1: An iminoaryl compound substituted with a carboxylic acid derivative, represented by the general formula (1'), characterized in that: Q represents a compound of the group of formulas (2); Y represents halogen, haloalkyl or cyano; Z represents halogen; M represents CH or N; X represents -CX¹X²-(alkyl)ₙ-, -alkyl-CX¹X²-(alkyl)ₙ- or -(CH₂)ʳ-; X¹, X² each independently represent H, halogen, cyano, amino, nitro, formyl, cyanoalkyl, hydroxyalkyl, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, alkoxy, alkylthio, alkylamino, haloalkoxy, haloalkylthio, alkylcarbonyl, alkoxycarbonyl , alkoxyalkyl, haloalkoxyalkyl, alkylaminoalkyl, aryl, heterocyclyl, arylalkyl or heterocyclic alkyl, wherein "alkyl", "alkenyl" and "alkynyl" are each independently unsubstituted or substituted with halogen, "cycloalkyl", "cycloalkylalkyl", "aryl", "heterocyclyl", "arylalkyl" and "heterocyclic alkyl" are each independently unsubstituted or substituted with at least one group selected from oxo, halogen, cyano, nitro, alkyl, alkenyl , alkynyl, cycloalkyl, haloalkyl, haloalkenyl, haloalkynyl, halocycloalkyl, alkyl-substituted cycloalkyl, -OR¹³, -SR¹³, -(CO)OR¹³, -(SO₂)R¹³, -N(R¹³)₂, and -O-alkyl-(CO )OR¹³, or two carbon atoms non-adjacent in the ring together with -OCH₂CH₂- or -OCH₂O- unsubstituted or substituted with halogen form a fused ring; and X¹, X² are not hydrogen at the same time; X³ represents O, S, NH or N-alkyl; Q¹, Q², Q³, Q⁴, Q⁵ each independently represent O or S; R¹, R² each independently represent H, cyano, alkyl, alkenyl, alkynyl, formylalkyl, cyanoalkyl, amino, aminoalkyl, aminocarbonyl, aminocarbonylalkyl, aminosulfonyl, cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, heterocyclyl, heterocyclic alkyl, aryl, arylalkyl, R⁴R⁵N-(CO)-NR³-, a moiety of formula (3), R³-S(O)ₘ-(alkyl)ₙ-, R³-O-(alkyl)ₙ-, R³-(CO)-( alkyl)ₙ-, R³-O-(alkyl)ₙ-(CO)-, R³-(CO)-O-(alkyl)ₙ-, R³-S-(CO)-(alkyl)ₙ-, R³-O -(CO)-alkyl- or R³-O-(CO)-O-alkyl-, wherein "alkyl", "alkenyl" and "alkynyl" are each independently unsubstituted or substituted with halogen, the "amino", "aminoalkyl", "aminocarbonyl", "aminocarbonylalkyl" and "aminosulfonyl" are each independently unsubstituted or substituted with one or two groups selected from -R¹¹, -OR¹¹, -(CO)R¹¹ , -(CO)OR¹¹, -alkyl-(CO)OR¹¹, -(SO₂)R¹¹, -(SO₂)OR¹¹, -alkyl-(SO₂)R¹¹, -(CO)N(R¹²)₂ and -(SO₂)N (R¹²)₂, the “cycloalk uyl", "cycloalkylalkyl", "cycloalkenyl", "cycloalkenylalkyl", "heterocyclyl", "heterocyclic alkyl", "aryl", and "arylalkyl" are each independently unsubstituted or substituted with at least one group selected from oxo, halogen, cyano, nitro, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, haloalkenyl, haloalkynyl, halocycloalkyl, alkyl-substituted cycloalkyl, -OR¹³, -SR¹³, -(CO)OR¹³, -(SO₂)R¹³, -N( R¹³)₂ and -O-alkyl-(CO)OR¹³, or two adjacent ring carbon atoms together with unsubstituted or halogen-substituted -OCH₂CH₂- or -OCH₂O- form a fused ring; R⁶ represents alkyl, alkenyl, alkynyl or cyano, wherein "alkyl", "alkenyl" and "alkynyl" are each independently unsubstituted or substituted with at least one group selected from halogen, alkoxy and alkoxycarbonyl; R⁷, R⁷', R⁸, R⁸' each independently represent H, alkyl, halogen, haloalkyl, amino, hydroxyalkyl or alkoxy; R³, R⁴, R⁵ each independently represent H, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, heterocyclyl, heterocyclic alkyl, aryl or arylalkyl, wherein “alkyl”, “alkenyl” and “ alkynyl" are each, independently, unsubstituted or substituted with halogen, the "cycloalkyl", "cycloalkylalkyl", "cycloalkenyl", "cycloalkenylalkyl", "heterocyclyl", "heterocyclic alkyl", "aryl" and "arylalkyl" are each independently unsubstituted or substituted with at least one group selected from oxo, halogen, cyano, nitro, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, haloalkenyl, haloalkynyl, halocycloalkyl, alkyl-substituted cycloalkyl, -OR¹³ , -SR¹³, -(CO)OR¹³, -(SO₂)R¹³, -N(R¹³)₂ and -O-alkyl-(CO)OR¹³, or two adjacent carbon atoms in the ring together with -OCH₂CH₂- or -OCH₂O - unsubstituted or substituted with halogen form a fused ring; R¹¹ independently represents alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, phenyl, benzyl, wherein "alkyl", "alkenyl" and "alkynyl" are each independently unsubstituted or substituted with halogen, "phenyl" and "benzyl" are each independently unsubstituted or substituted with at least one group selected from halogen, cyano, nitro, alkyl, haloalkyl, alkoxycarbonyl, alkylthio, alkylsulfonyl, alkoxy, and haloalkoxy ; R¹² independently represents H, alkyl, alkenyl, alkynyl, alkoxy, alkylsulfonyl, cycloalkyl, cycloalkylalkyl, cycloalkenyl, or cycloalkenylalkyl, or N(R¹²)₂ in -(CO)N(R¹²)₂ or -(SO₂)N( R¹²)₂ each independently represent unsubstituted or substituted heterocyclyl with nitrogen atom in position 1; R¹³ independently represents H, alkyl, haloalkyl, phenyl, or phenyl substituted with at least one group selected from halogen, cyano, nitro, alkyl, haloalkyl, alkoxycarbonyl, alkylthio, alkylsulfonyl, alkoxy, and haloalkoxy; r represents an integer of 2 or more; m represents 0, 1 or 2; n independently represents 0 or 1; derivative means that the carboxylic acid functional group in the general formula is changed to any ester, acylhydrazide, imidate, thioimidate, amidine, amide, orthoester, acyl cyanide, acyl halide, thioester, thionoester, dithioester, nitrile, or any other derivative of carboxylic acid. |
| priorityDate | 2020-01-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 32.