http://rdf.ncbi.nlm.nih.gov/pubchem/patent/AR-119074-A1

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filingDate 2020-06-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_46e16097a8a0083ec0461293b07dfc8f
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publicationDate 2021-11-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber AR-119074-A1
titleOfInvention 1-PHENYL-5-AZINILPYRAL-3-OXYALKYL ACIDS AND THEIR USE TO COMBAT UNWANTED PLANT GROWTH
abstract Claim 1: Compounds of the general formula (1) and their agrochemical compatibility salts, characterized in that A is selected from the group consisting of A1 - A15 of the group of formulas (2); R¹ was selected from the group consisting of OR¹ᵃ and NR⁹R¹⁰; wherein R¹ᵃ was selected from the group consisting of hydrogen; C₁₋₆ alkyl, C₃₋₆ cycloalkyl which is unsubstituted or substituted with one or more substituents selected from the group consisting of halogen, C₁₋₆ alkyl, C₁₋₆ halogenoalkyl, C₃₋₆ cycloalkyl, C₁₋ alkoxy ₆, cyano and nitro; C₂₋₄ alkenyl, C₂₋₄ alkynyl; C₁₋₄-alkyl-SO-C₁₋₄, C₁₋₄-alkyl-SO₂-C₁₋₄; heterocyclyl-C₁₋₄-alkyl, heteroaryl-C₁₋₄-alkyl and aryl-C₁₋₄-alkyl, where aryl, heterocyclyl and heteroaryl are unsubstituted or substituted with halogen, C₁₋₆-alkyl and/or C₁₋₆-haloalkyl; R⁹ is selected from the group consisting of hydrogen, C₁₋₁₂ alkyl; R¹⁰ is selected from the group consisting of hydrogen; aryl, heteroaryl, heterocyclyl; C₁₋₁₂ alkyl; C₃₋₈-cycloalkyl, C₃₋₇-cycloalkyl-C₁₋₇-alkyl; C₂₋₁₂ alkenyl, C₅₋₇ cycloalkenyl, C₂₋₁₂ alkynyl; S(O)ₙR⁵, cyano, nitro, OR⁵, SO₂NR⁶R⁷, CO₂R⁸, COR⁸, NR⁶R⁸, NR⁶COR⁸, NR⁶CO₂R⁸, NR⁶SO₂R⁸; which are unsubstituted or in each case independently substituted with m radicals which are selected from the group consisting of hydrogen, halogen, cyano, nitro, OR⁵, S(O)ₙR⁵, SO₂NR⁶R⁷, CO₂R⁸, CONR⁶R⁸, COR⁶ , NR⁶R⁸, NR⁶COR⁸, NR⁶CONR⁸R⁸, NR⁶CO₂R⁸, NR⁶SO₂R⁸, NR⁶SO₂NR⁶R⁸, C(R⁶)=NOR⁸; or R⁹ and R¹⁰ together with the nitrogen atom to which they are attached form a ring which is optionally substituted one to six times with radicals from the group consisting of halogen, C₁₋₆-alkyl, C₁₋₆-halogenoalkyl, OR⁵, S( O)ₙR⁵, CO₂R⁸, CONR⁶R⁸, COR⁶ and C(R⁶)=NOR⁸, saturated, partially or totally unsaturated and is composed of 5, 6 or 7 members, which in addition to this nitrogen atom contains r carbon atoms, or carbon atoms oxygen, p sulfur atoms and q elements of the group consisting of NR⁷, CO and NCOR⁷ as ring atoms; R⁵ means C₁₋₈ alkyl, C₃₋₆ cycloalkyl, C₁₋₆ halogenoalkyl or aryl; R⁶ means hydrogen or R⁵; R⁷ stands for hydrogen, C₁₋₆ alkyl, C₃₋₆ cycloalkyl, C₃₋₄ alkenyl or C₃₋₄ alkynyl; R⁸ stands for hydrogen, C₁₋₆ alkyl, C₃₋₆ cycloalkyl, C₃₋₄ alkenyl or C₃₋₄ alkynyl; R² is selected from the group consisting of hydrogen, and cyano; C₁₋₆ alkyl, C₁₋₄ alkoxy-C₁₋₄ alkyl, C₁₋₆ halogenoalkyl, C₁₋₆ alkoxy; C₂₋₆ alkenyl, C₂₋₆ halogenoalkenyl; C₂₋₆ alkynyl, C₂₋₆ halogenoalkynyl; C₃₋₆ cycloalkyl; R³ is selected from the group consisting of hydrogen, halogen, cyano, isocyano, NO₂; C₁₋₆ alkyl, C₁₋₆ halogenoalkyl, C₁₋₆ alkylcarbonyl, C₁₋₆ haloalkylcarbonyl, C₁₋₄ alkyloxycarbonyl; C₂₋₃ alkenyl, C₂₋₃ halogenoalkenyl; C₂₋₃ alkynyl, C₂₋₃ halogenoalkynyl; C₁₋₂-alkyl-S(O)ₙ and C₁₋₂-haloalkyl-S(O)ₙ; CHO; NH₂; R⁴ is phenyl, where the phenyl moiety is unsubstituted or mono- or polysubstituted with a moiety selected from the group consisting of hydrogen, halogen, cyano, isocyano, nitro; C₁₋₆ alkyl, halogeno-C₁₋₆ alkyl, halogeno-C₁₋₃ alkoxy; C₂₋₃ alkenyl, halogeno-C₂₋₃ alkenyl, C₁₋₆ alkoxy; C₂₋₃-alkynyl, halogeno-C₂₋₃-alkynyl, C₁₋₄-alkyl-S(O)ₙ; CHO, C₁₋₄ alkyloxycarbonyl, and NH₂; R¹² is selected from the group consisting of hydrogen, halogen, cyano, isocyano, NO₂; C₁₋₆-alkyl, C₁₋₆-halogenoalkyl, C₁₋₆-alkylcarbonyl, C₁₋₆-haloalkylcarbonyl, C₁₋₄-alkyloxycarbonyl, C₁₋₆-alkoxy, C₁₋₃-halogenoalkoxy, C₁₋₄-alkyl-S(O)ₙ; C₂₋₃ alkenyl, C₂₋₃ halogenoalkenyl; C₂₋₃ alkynyl, C₂₋₃ halogenalkynyl; NH₂; and in which the continuous number means m 0, 1 or 2; n 0, 1 or 2; or 0, 1 or 2; p 0 or 1; q 0 or 1; r 3, 4, 5 or 6; and s 0, 1 or 2.
priorityDate 2019-06-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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