http://rdf.ncbi.nlm.nih.gov/pubchem/patent/AR-114430-A1

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filingDate 2019-03-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_835d90e9878931df3743dc7830e22ea0
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publicationDate 2020-09-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber AR-114430-A1
titleOfInvention HERBICIDE COMPOUNDS
abstract Claim 1: A compound of formula (1) wherein R¹ is methyl; R² is methyl or methoxy; R³ is methyl or methoxy; R⁴ is selected from the group consisting of -S (O) ₙ-C₁₋₆ alkyl, -S (O) ₙ-C₁₋₆ haloalkyl, -S (O) ₙ- (CH₂) ₙ-C₃₋₆ cycloalkyl, -S (O) ₙC (R¹¹) R¹²R¹³, -C (O) H, -C (O) - (CH₂) ₙ-C₃₋₆ cycloalkyl, -C (O) C (R¹¹) R¹²R¹³, -C (O) C₂₋₄ alkenyl, -C (O) (CR⁹R¹⁰) CN, -C (O) (CR⁹R¹⁰) (CR⁹R¹⁰) CN, -C (O) CH₂C (O) -C₁₋₆alkyl, -C (O) CH₂OC ( O) -C₁₋₆ alkyl, -C (O) O-C₁₋₆ alkyl, -C (O) O-C₁₋₆ haloalkyl, -C (O) (CR⁹R¹⁰) ₙS (O) ₙ-C₁₋₆ alkyl , -C (O) C alkoxy C₁₋₃alkyl, -C (O) C₂₋₆ C₁₋₃alkenyl alkoxy, -C (O) C₂₋₆ C₁₋₃alkynyl alkoxy, -C (O) C₁ C₁₋₃haloalkyl alkoxy ₋₆, -C (O) C₃₋₆Ccycloalkyl alkoxy, -C (O) O-C₁₋₆alkyl Calkoxy, -C (O) C₁₋₆Calkoxy C₁₋₃alkyl alkoxy, -C ( O) (CH₂) ₙNR⁵R⁶, -C (O) - (CH₂) ₙ-NR⁷C (O) R⁸, -C (O) - (CH₂) ₙ-ON = CR⁵R⁵, -CN, - (CH₂) ₙ-phenyl, -C (O) - (CH₂) ₙ-phenyl, -S (O) ₙ- (CH₂) ₙ-phenyl, -heterocyclyl, -C (O) - (CH₂) ₙ-heterocyclyl, -C (O) (CH₂ ) ₙO- (CH₂) ₙ-heterocyclyl, -S (O) ₙ- (CH₂) ₙ-heterocyclyl, where each heterocyclyl is a 5- or 6-membered heterocyclyl that can be aromatic, saturated, or partially saturated or and may contain 1 to 4 heteroatoms each independently selected from the group consisting of oxygen, nitrogen, and sulfur and wherein said heterocyclyl or phenyl groups are optionally substituted with one, two, or three substituents independently selected from the group consisting of alkyl C₁₋₃, C₁₋₃ haloalkyl, C₁₋₃ alkoxy, C₂₋₃ alkenyl, C₂₋₃ alkynyl, halogen, cyano, and nitro; R⁵ is selected from the group consisting of hydrogen and C₁₋₆ alkyl; R⁶ is selected from the group consisting of hydrogen, C₁₋₆ alkyl, C₂₋₆ alkenyl, C₂₋₆ alkynyl, C₁₋₆ haloalkyl, hydroxyl-, C₁₋₆ alkoxy, C₃₋₆ cycloalkyl, -C₁₋₆ alkoxy Calalkyl ₋₆, -alkoxy C₁₋₃-haloalkyl, - (CR⁹R¹⁰) haloalkyl C₁₋₆, - (CR⁹R¹⁰) C (O) NR⁵R⁵, phenyl, pyridyl, wherein the phenyl and pyridyl are optionally substituted with one, two or three substituents independently selected from the group consisting of C₁₋₃ alkyl, C₁₋₃ haloalkyl, C₁₋₃ alkoxy, C₂₋₃ alkenyl, C₂₋₃ alkynyl, halogen, cyano, and nitro; or R⁵ and R⁶ together form -CH₂CH₂OCH₂CH₂-; and R⁷ is selected from the group consisting of hydrogen and C₁₋₆ alkyl; R⁸ is selected from the group consisting of hydrogen, C₁₋₆ alkyl, C₁₋₆ alkoxy, C₃₋₆ cycloalkyl, phenyl, pyridyl, wherein phenyl and pyridyl are optionally substituted with one, two, or three substituents independently selected from the group consisting of C₁₋₃ alkyl, C₁₋₃ haloalkyl, C₁₋₃ alkoxy, C₂₋₃ alkenyl, C₂₋₃ alkynyl, halogen, cyano, and nitro; R⁹ is hydrogen or methyl; R¹⁰ is hydrogen or methyl; or R⁹ and R¹⁰ together form -CH₂CH₂-; and R¹¹ is hydrogen or methyl; R¹² is selected from the group consisting of hydrogen, C₁₋₆ alkyl, hydroxyl, and C₁₋₆- alkoxy; R¹³ is selected from the group consisting of hydrogen, C₁₋₆ alkyl, hydroxyl, and C₁₋₆ alkoxy; or R¹² and R¹³ together form -CH₂-X-CH₂-; and X is selected from the group consisting of O, S, and N-R¹⁴; R¹⁴ is selected from the group consisting of hydrogen, C₁₋₃ alkyl, and C₁₋₃-alkoxy; n is 0, 1 or 2; G is selected from the group consisting of hydrogen, - (CH₂) ₙ-Rᵃ, -C (O) -Rᵃ, -C (O) - (CRᶜRᵈ) ₙ-O-Rᵇ, -C (O) - (CRᶜRᵈ ) ₙ-S-Rᵇ, -C (O) NRᵃRᵃ, -S (O) ₂-Rᵃ and C₁₋₈alkyl-C₁₋₃- alkoxy; Rᵃ is independently selected from the group consisting of hydrogen, C₁₋₈ alkyl, C₁₋₃ haloalkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₃₋₆ cycloalkyl, heterocyclyl, and phenyl, wherein said heterocyclyl and phenyl groups are optionally substituted with one, two, or three substituents independently selected from the group consisting of C₁₋₃ alkyl, C₁₋₃ haloalkyl, C₁₋₃ alkoxy, C₂₋₃ alkenyl, C₂₋₃ alkynyl, halogen, cyano, and nitro; Rᵇ is selected from the group consisting of C₁₋₈ alkyl, C₁₋₃ haloalkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₃₋₆ cycloalkyl, heterocyclyl, and phenyl, wherein said heterocyclyl and phenyl groups are optionally substituted with one , two or three substituents independently selected from the group consisting of C₁₋₃ alkyl, C₁₋₃ haloalkyl, C₁₋₃ alkoxy, C₂₋₃ alkenyl, C₂₋₃ alkynyl, halogen, cyano, and nitro; Rᶜ is hydrogen or C₁₋₃ alkyl; and Rᵈ is hydrogen or C₁₋₃ alkyl; or an agriculturally acceptable salt thereof.
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