http://rdf.ncbi.nlm.nih.gov/pubchem/patent/AR-113769-A1

Outgoing Links

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filingDate 2018-10-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_29e71338f70c04f98c191e3ae5cd03d1
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publicationDate 2020-06-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber AR-113769-A1
titleOfInvention PROCESS TO PREPARE PYRIDAZINONE-DERIVED HERBICIDES
abstract Process for preparing herbicides derived from pyridazinone of formula (1). Claim 1: A process for producing a compound of formula (1), where R¹ is selected from the group consisting of hydrogen, C₁₋₆ alkyl, C₁₋₆ haloalkyl, (C₁₋₃ alkoxy) (C₁₋₃ alkyl) - , (C₁₋₃ alkoxy) (C₂₋₃ alkoxy) (C₁₋₃ alkyl) -, aryl, and a 5- or 6-membered heteroaryl, wherein the heteroaryl contains one to three heteroatoms each independently selected from the group consisting of oxygen, nitrogen and sulfur, and where the aryl and heteroaryl component may be optionally substituted; R² is C₁₋₆ alkyl or C₃₋₆ cycloalkyl; A¹ is selected from the group consisting of O, C (O), and (CR⁷R⁸); and R⁴, R⁶, R⁷, and R⁸ are each independently selected from the group consisting of hydrogen and C₁₋₄ alkyl; R³ and R⁵ are each independently selected from the group consisting of hydrogen and C₁₋₄ alkyl or together they may form a C₁₋₃ alkylene chain; the process comprising reacting a compound of formula (2), where X is a halogen; with a compound of formula (3), where A¹ and R³, R⁴, R⁵ and R⁶ are as defined with respect to formula (1) above; in a reaction medium comprising: (i) a palladium catalyst; (ii) a suitable phosphine-type ligand or phosphine-type ligand salt; (iii) a suitable basis; and (iv) carbon monoxide; to obtain a compound of formula (1).
priorityDate 2017-10-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 31.