http://rdf.ncbi.nlm.nih.gov/pubchem/patent/AR-095303-A1

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D401-04
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filingDate 2014-03-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f3547280823285df2ddefc1031624af1
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publicationDate 2015-10-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber AR-095303-A1
titleOfInvention 4-AMINO-6- (PIRIDIL AND PHENYL 2-REPLACED) -PICOLINATES AND 6-AMINO-2- (PIRIDIL AND PHENYL 2-REPLACED) -PIRIMIDIN-4 CARBOXYLATES AND THEIR USE AS HERBICIDES
abstract Claim 1: A compound of the formula (1) wherein X is N or CY, wherein Y is hydrogen, halogen, C₁₋₃ alkyl, C₁₋₃ haloalkyl, C₁₋₃ alkoxy, C₁₋₃ haloalkoxy, C₁₋ alkyl ₃-thio or halo-C₁₋₃-thio alkyl; R¹ is OR¹, where R¹ is H, C₁₋₈ alkyl or C₇₋₁₀ arylalkyl; R² is halogen, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₂₋₄ alkenyl, C₂₋₄ haloalkenyl, C₂₋₄ alkynyl, C₂₋₄ haloalkynyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄-thio alkyl , haloCquil-thio alkyl, amino, C₁₋₄-amino alkyl, C₂₋₄-amino haloalkyl, formyl, (C₁₋₃ alkyl) carbonyl, (haloC halo alkyl) carbonyl, cyano or a group of the formula - CR¹⁷ = CR¹⁸-SiR¹⁹R²⁰R²¹, where R¹⁷ is hydrogen, F or Cl; R¹⁸ is hydrogen, F, Cl, C₁₋₄ alkyl or C₁₋₄ haloalkyl; and R¹⁹, R²⁰ and R²¹ are, independently, C₁₋₁₀ alkyl, C₃₋₆ cycloalkyl, C₁₋₁₀ haloalkyl, C₃₋₆ halocycloalkyl, phenyl, substituted phenyl, C₁₋₁₀ or OH alkoxy; R³ and R⁴ are, independently, hydrogen, C₁₋₆ alkyl, C₁₋₆ haloalkyl, C₃₋₆ alkenyl, C₃₋₆ haloalkenyl, C₃₋₆ alkynyl, C₃₋₆ haloalkynyl, hydroxy, C₁₋₆ alkoxy, C₁ haloalkoxy ₋₆, formyl, (C₁₋₃ alkyl) carbonyl, (haloCquil alkyl) carbonyl, (C₁₋₆ alkoxy) carbonyl, (C₁₋₆ alkyl) carbamyl, (C₁₋₆ alkyl) sulfonyl, tri (C₁₋ alkyl) ₆) silyl, di (C₁₋₆ alkyl) phosphonyl or R³ and R⁴ taken together with the nitrogen atom to which they are attached form a saturated or unsaturated ring of 5 or 6 members or R³ and R⁴ taken together represent = CR³R⁴, where R³ and R⁴ are independently hydrogen, C₁₋₆ alkyl, C₃₋₆ alkenyl, C₃₋₆ alkynyl, C₁₋₆ alkoxy or C₁₋₆-amino alkyl or R³ and R⁴ taken together with the carbon atom to which they are joined form a saturated ring of 5 or 6 members; Ar is selected from the group consisting of formulas (2), (3), (4), (5), (6) and (7), where W¹ is F; W² is hydrogen or F; W³ is Cl, Br, I, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₂₋₄ alkenyl, C₂₋₄ haloalkenyl, C₂₋₄ alkynyl, C₂₋₄ haloalkynyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁ alkyl ₋₄-thio or halo-C₁₋₄-thio alkyl; X¹ is hydrogen, F, Cl, Br, I, C₁₋₄ alkyl, C₁₋₄ haloalkyl, cyclopropyl, halocyclopropyl, C₁₋₄ alkoxy or C₁₋₄ haloalkoxy; X² is hydrogen, F, Cl, Br, I, C₁₋₄ alkyl, C₁₋₄ haloalkyl, cyclopropyl, halocyclopropyl, C₂₋₄ alkenyl, C₂₋₄ haloalkenyl, C₂₋₄ alkynyl, C₂₋₄ haloalkynyl, C₁₋₄ alkoxy , haloalkoxy C₁₋₄, CN, CONH₂, CO₂H or NO₂; X³ is F, Cl, Br, I, C₁₋₄ alkyl, C₁₋₄ haloalkyl, cyclopropyl, halocyclopropyl, C₂₋₄ alkenyl, C₂₋₄ haloalkenyl, C₂₋₄ alkynyl, C₂₋₄ haloalkynyl, C₁₋₄ alkoxy, haloalkoxy C₁₋₄, CN, CONH₂, CO₂H or NO₂; Y¹ is halogen, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₂₋₄ alkenyl, C₂₋₄ haloalkenyl, C₂₋₄ alkynyl, C₂₋₄ haloalkynyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄-thio alkyl , C₁₋₄-thio haloalkyl, amino, C₁₋₄-amino alkyl, C₁₋₄-amino haloalkyl, C₁₋₆ alkyl substituted with (C₁₋₆ alkoxy), CN or NO₂; Y² is hydrogen or F; Z¹ is halogen, C₁₋₄ alkyl, C₁₋₄ haloalkyl, cyclopropyl, C₂₋₄ alkenyl, C₂₋₄ haloalkenyl, C₂₋₄ alkynyl, C₂₋₄ haloalkynyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄ alkyl -thio or halo-C₁₋₄-thio alkyl; Z² is hydrogen, halogen, C₁₋₄ alkyl, C₁₋₄ haloalkyl, cyclopropyl, C₂₋₄ alkenyl, C₂₋₄ haloalkenyl, C₂₋₄ alkynyl, C₂₋₄ haloalkynyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁ alkyl ₋₄-thio or halo-C₁₋₄-thio alkyl; Z³ is Cl, Br, I, C₁₋₄ alkyl, C₁₋₄ haloalkyl, cyclopropyl, C₂₋₄ alkenyl, C₂₋₄ haloalkenyl, C₂₋₄ alkynyl, C₂₋₄ haloalkynyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄-thio alkyl or C₁₋₄-thio haloalkyl; Z⁴ is C₁₋₄ alkyl, C₁₋₄ haloalkyl, cyclopropyl, C₂₋₄ alkenyl, C₂₋₄ haloalkenyl, C₂₋₄ alkynyl, C₂₋₄ haloalkynyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄-thio alkyl or halo-C₁₋₄-thio alkyl; and where when Ar is: g) the compound of formula (2) then X is N, CH, CF, CCl or CCH₃; provided that v) X¹ is not hydrogen, F, Cl or OCH₃ when R² is Cl or vinyl and X is N; vi) X¹ is not hydrogen, Cl or OCH₃ when R² is Cl and X is CH; vii) X¹ is not Cl when R² is Cl and X is CF; and viii) X¹ is not CF₃, cyclopropyl or OCH₃ when R² is OCH₃ and X is CF; h) the compound of formula (3) then X is N, CH or CF; provided that X¹ is not hydrogen, CH₃ or OCH₃ when R² is Cl and X is N; i) the compound of formula (4) then X is N, CH or CF; j) the compound of formula (5) then X is N, CH or CF; k) the compound of formula (6) then X is N, CH or CF; and l) the compound of formula (7) then X is N, CH or CF; provided that W³ is not Cl, CH₃, CF₃ or OCH₃ when Y² is hydrogen; or one of its N-oxides or salts acceptable in agriculture.
priorityDate 2013-03-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 38.