http://rdf.ncbi.nlm.nih.gov/pubchem/patent/AR-094060-A1

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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2bbcd4c14fdee5bf8b15ed18a300236c
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publicationDate 2015-07-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber AR-094060-A1
titleOfInvention TETRAHYDRONAFTIL (UNCLE) CARBOXAMIDS
abstract This refers to tetrahydronaphthyl (thio) carboxamides, the processes for preparing these compounds, the compositions comprising these compounds, and their use as biologically active compounds, especially for controlling harmful microorganisms in crop protection and material protection Claim 1: Tetrahydronaphthyl (thio) carboxamides of the formula (1) wherein Het represents a radical selected from the group of formulas Het1 to Het11; X¹, X² and X³ independently represent hydrogen; halogen; cyano; nitro, hydroxyl; C₁₋₁₆ alkyl, C₁₋₆ haloalkyl having 1 to 9 identical or different halogen atoms; C₃₋₇ cycloalkyl, C₃₋₇ halocycloalkyl having 1 to 9 identical or different halogen atoms; C₁₋₆ alkoxy; C₁₋₆ haloalkoxy having 1 to 9 identical or different halogen atoms; with the proviso that when Het represents Het¹, X¹ is not difluoro- or dichloromethyl and X² is not chlorine or fluorine; T represents an oxygen or sulfur atom; Q represents hydrogen, C₁₋₆sulfonyl alkyl, C₁₋₄ alkoxy-C₁₋₄ alkyl, haloCquilsulfonyl alkyl, halo haloC alco alkoxy-C₁₋₄ alkyl; X represents halogen, nitro, cyano, C₁₋₁₂ alkyl; C₁₋₆ haloalkyl having 1 to 9 identical or different halogen atoms; C₁₋₆ alkoxy; C₁₋₆ haloalkoxy having 1 to 9 identical or different halogen atoms; C₁₋₆sulfanyl alkyl; haloalkyl C₁₋₆sulfanyl having 1 to 9 identical or different halogen atoms; C₁₋₆sulfonyl alkyl; haloalkyl C₁₋₆sulfonyl having 1 to 9 identical or different halogen atoms; C₂₋₁₂ alkenyl; C₂₋₁₂ alkynyl; C₃₋₇ cycloalkyl; phenyl; trialkyl C₁₋₈silyl; trialkyl C₁₋₈silyl-C₁₋₈ alkyl; m represents, 1, 2 or 3; R¹, R², R³, R⁴, R⁵, R⁶, R⁷ and R⁸ independently represent each other hydrogen; halogen; cyano; C₁₋₁₆ alkyl; C₂₋₁₆ haloalkyl having 1 to 9 identical or different halogen atoms; C₃₋₈ cycloalkyl; C₃₋₇ halocycloalkyl having 1 to 9 identical or different halogen atoms; C₁₋₆ haloalkyl having 1 to 9 identical or different halogen atoms; (C₃₋₈ cycloalkyl) -C₁₋₈ alkyl; (C₃₋₈ cycloalkyl) -C₃₋₈ cycloalkyl; C₂₋₁₆ alkenyl; C₂₋₁₆ alkynyl; C₂₋₁₆-Cque-alkyl alkenyl; C₂₋₁₆ alkynyl-C₁₋₁₆ alkyl; C₁₋₁₆ alkoxy; C₃₋₈ cycloalkyloxy; (C₃₋₈ cycloalkyl) -C₁₋₈ alkyloxy; C₁₋₈sulfanyl alkyl; C₃₋₈sulfanyl cycloalkyl; (C₃₋₈ cycloalkyl) -C₁₋₈sulfanyl alkyl; C₂₋₁₆ alkenyloxy; C₃₋₈ alkynyloxy; aryl C₁₋₈ alkyloxy which is optionally substituted with up to 6 identical or different Rᵇ groups; aryl-C₁₋₈sulfanyl alkyl which is optionally substituted with up to 6 identical or different Rᵇ groups; aryloxy which is optionally substituted with up to 6 identical or different Rᵇ groups; arylsulfanyl which is optionally substituted with up to 6 identical or different Rᵇ groups; (C₃₋₈ cycloalkyl) -C₂₋₈ alkenyl; (C₃₋₈ cycloalkyl) -C₂₋₈ alkynyl; trialkyl C₁₋₈silyl; trialkyl C₁₋₈silyl-C₁₋₈ alkyl; aryl-C₁₋₈ alkyl which is optionally substituted with up to 6 identical or different Rᵇ groups; C₂₋₈-aryl-alkenyl which is optionally substituted with up to 6 identical or different Rᵇ groups; aryl-Cil alkynyl which is optionally substituted with up to 6 identical or different Rᵇ groups; C₁₋₈ alkylamino; di-Cila alkylamino; arylamino which is optionally substituted with up to 6 identical or different Rᵇ groups; C₁₋₈carbonyl alkyl; C₁₋₈carbonyloxy alkyl; C₁₋₈-carbonylamino alkyl; C₁₋₈carbonyl alkoxy; C 1 -carbonyloxy alkyloxy; C₁₋₈-carbonyloxy alkylamino; di-alkylamino C₁₋₈-carbonyloxy; N- (C₁₋₈ alkyl) hydroxycarbamoyl; C₁₋₈carbamoyl alkoxy; N- (C₁₋₈ alkyl) -C₁₋₈carbamoyl alkoxy; aryl-C₁₋₈ alkylamino which is optionally substituted with up to 6 identical or different Rᵇ groups; (C₁₋₆ alkoxyimino) -C₁₋₈ alkyl; (C₂₋₈ cycloalkoxyimino) -C₁₋₈ alkyl; C₁₋₈ alkyliminoxy; C₁₋₆-C-alkyliminoxy; each of which is optionally substituted; wherein one or more substituents of the selected group of R¹, R², R³, R⁴, R⁵, R⁶, R⁷ and R⁸ does not represent hydrogen; or R¹ and R² together with the carbon to which a C₃₋₈ cycloalkyl is attached; C₃₋₈ cycloalkenyl, each of which is optionally substituted; or it can represent a group = C (Y¹) Y² or an N-O-Rᶜ group; R³ and R⁴ together with the carbon to which a C₃₋₈ cycloalkyl is attached; C₃₋₈ cycloalkenyl, each of which is optionally substituted; or it can represent a group = C (Y¹) Y² or an N-O-Rᶜ group; R⁵ and R⁶ together with the carbon to which a C₃₋₈ cycloalkyl is attached; C₃₋₈ cycloalkenyl, each of which is optionally substituted; or it can represent a group = C (Y¹) Y² or an N-O-Rᶜ group; R⁷ and R⁸ together with the carbon to which a C₃₋₈ cycloalkyl is attached; C₃₋₈ cycloalkenyl, each of which is optionally substituted; or it can represent a group = C (Y¹) Y² or a group = N-O-Rᶜ; R¹ and R³ represent with the carbons to which a C₃₋₈ cycloalkyl is attached; C₃₋₈ cycloalkenyl, each of which is optionally substituted; R³ and R⁵ represent with the carbons to which a C₃₋₈ cycloalkyl is attached; C₃₋₈ cycloalkenyl, each of which is optionally substituted; R⁵ and R⁷ represent with the carbons to which a C₃₋₈ cycloalkyl is attached; C₃₋₈ cycloalkenyl, each of which is optionally substituted; Rᵇ represents halogen; nitro, cyano, C₁₋₁₂ alkyl; C₁₋₆ haloalkyl having 1 to 9 identical or different halogen atoms; C₁₋₆ alkoxy; C₁₋₆ haloalkoxy having 1 to 9 identical or different halogen atoms; C₁₋₆sulfanyl alkyl; haloalkyl C₁₋₆sulfanyl having 1 to 9 identical or different halogen atoms; C₁₋₆sulfonyl alkyl; haloalkyl C₁₋₆sulfonyl having 1 to 9 identical or different halogen atoms; C₂₋₁₂ alkenyl; C₂₋₁₂ alkynyl; C₃₋₇ cycloalkyl; phenyl; trialkyl C₁₋₈silyl; trialkyl C₁₋₈silyl-C₁₋₈ alkyl; Y¹ and Y² independently represent one another hydrogen, halogen, C₁₋₁₂ alkyl; C₁₋₆ haloalkyl having 1 to 9 identical or different halogen atoms; C₁₋₈sulfanyl alkyl; phenyl; each of which is optionally substituted; or Y¹ and Y² can form together with the carbon to which a C₃₋₈ cycloalkyl or a C₃₋₈ cycloalkenyl or a saturated 5, 6 or 7 membered heterocycle are attached; each of which is optionally substituted; Rᶜ represents C₁₋₁₆ alkyl; C₁₋₆ haloalkyl having 1 to 9 identical or different halogen atoms; C₃₋₈ cycloalkyl; (C₃₋₈ cycloalkyl) -C₁₋₈ alkyl; (C₃₋₈ cycloalkyl) -C₃₋₈ cycloalkyl; C₂₋₈-Cque-alkyl alkenyl; C₂₋₈ alkynyl-C₁₋₁₆ alkyl; aryl-C₁₋₈ alkyl which is optionally substituted with up to 6 identical or different Rᵇ groups; each of which is optionally substituted.
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