http://rdf.ncbi.nlm.nih.gov/pubchem/patent/AR-080113-A1
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_60e5945bbb40ece5358ca6b1db4a45be |
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-70 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-72 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-0216 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-72 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01F25-431 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-582 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-96 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2219-00094 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-182 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01F25-40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D301-03 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J4-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D301-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01D17-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01D17-0208 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J19-2435 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D301-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J19-18 |
| filingDate | 2011-02-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4f9c5d93867ad79d9b9e2ffc577f957e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_64dac75bdc04bb7636311438449648a8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b9117e26eb5d7cd6c517abe645a7ec4c http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5cff63b3b59da0b35dc5621cd995fd3d http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2b5d9f9fa289dc1569a9744e5fcbc62d http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e4dd43af93032f1fcf56657649996f21 |
| publicationDate | 2012-03-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | AR-080113-A1 |
| titleOfInvention | PROCESS FOR THE MANUFACTURE OF 1,2-EPOXIDES AND DEVICE TO CARRY OUT THIS PROCESS |
| abstract | Apparatus and processes to form epoxy compounds. In one embodiment, a process is provided for the manufacture of an epoxide that includes adding an oxidant, a water-soluble manganese complex and a terminal olefin to form a multiphasic reaction mixture, reacting the terminal olefin with the oxidant in the multiphasic reaction mixture having at least one organic phase in the presence of the water soluble manganese complex, separating the reaction mixture into the at least one organic phase and an aqueous phase, and reusing at least part of the phase watery Device to perform the previous process. Claim 1: A process for the manufacture of an epoxide, characterized in that it comprises: a) adding an oxidant, a water-soluble manganese complex, and a terminal olefin to form a multiphasic reaction mixture, where the water-soluble manganese complex it is a mononuclear species that has the general formula: [LMnX3] Y or a binuclear species that has the general formula: [LMn (mi-X) 3MnL] (Y) n where Mn is manganese; L or each of the L is independently a polydentate ligand, each X is independently a coordinating species and each mi-X is independently a coordinating species that forms a bridge, and where Y is a non-coordinating counterion; b) reacting the terminal olefin with the oxidant in the multi-phase reaction mixture having at least one organic phase in the presence of the water soluble manganese complex; c) separating the reaction mixture into the at least one organic phase and an aqueous phase; and d) reuse at least part of the aqueous phase. Claim 15: A device (10) for carrying out the process of preceding claims 1 to 14, characterized in that it comprises: a reactor (10) for performing catalytic oxidation, which has an intake (10) for the oxidant feed, the water-soluble manganese complex, optionally the pH buffer solution and the terminal olefin to the reactor (10), and an outlet (22) for discharging the reaction mixture from said reactor (20), a separation means (30) connected to the reactor outlet (22) to separate the reaction mixture in the at least one organic phase and the aqueous phase, recycling means (40) to recycle part of the aqueous phase that separates into the separation medium ( 30), dispersion means (23) for dispersing the organic phase in the aqueous phase and cooling means (24) for controlling the temperature of the catalytic oxidation process. |
| priorityDate | 2010-02-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 36.