http://rdf.ncbi.nlm.nih.gov/pubchem/patent/AR-068061-A1
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_173bc2c63b34988699010ba05e5b1376 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D417-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D409-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D405-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D401-14 |
| filingDate | 2008-08-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2009-11-04-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | AR-068061-A1 |
| titleOfInvention | USEFUL BICYCLE DERIVATIVES AS PESTICIDES |
| abstract | Bicyclic bisamide derivatives that can be used as agrochemical active ingredients. Claim 1: A compound of formula (1) wherein G1, G2 and G3 form together with the two carbon atoms to which G1 and G3 are attached, a 5-membered aromatic ring system; where G1 is nitrogen or C-R5a; G2 is nitrogen or C-R5b; G3 is nitrogen or C-R5c; under the conditions that; d) at least one substituent G represents nitrogen; e) the group -X1-Y1 is attached to a nitrogen in the 5-membered ring; f) the group -X1-Y1 is different from methyl; X1 is oxygen, -C (O) -, - (CO) O-, thio, sulfinyl, sulfonyl, -SO2NR5d, -C (S) -, -P (= O) O (R5e) -, -C (O ) S-, -C (S) O-, -C (S) NR5f-, - (CO) NR5g-, or a direct link; Y1 is C1-30 alkyl. C3-30 alkenyl or C3-30 alkynyl which may be interrupted once, twice, three, four or five times by atoms or group of atoms independently selected from the group consisting of oxygen, sulfur, sulfinyl, sulfonyl, -C (O) - , -OC (O) - and -NR5h-, with the proviso that the interruption atoms are separated from each other by at least one methylene group; and which may be substituted once or several times with substituents selected from the group consisting of halogen, hydroxyl, amino, formyl, nitro, cyano, mercapto, carbamoyl, C3-6silyl trialkyl, C1-6 alkoxy, C1-6 alkoxycarbonyl, C2 alkenyl -5, C2-6 haloalkenyl, C2-6 alkynyl, C2-6 haloalkynyl, C3-6 alkenyloxy, C3-6 alkynyloxy, C1-6 haloalkoxy, C3-6 haloalkenyloxy, C1-6 cyanoalkoxy, C1-6 alkoxy C1-6 alkoxy, C1-6 alkoxy-C1-6 alkoxy-C1-6 alkoxy, C1-6 alkylthio-C1-6 alkoxy, C1-6 alkylfinyl-C1-6 alkoxy, C1-6sulfonyl-C1-6 alkoxy, C 1-6 alkoxycarbonyl-C 1-6 alkoxy, C 1-6 alkoxycarbonyl, C 1-6 alkylcarbonyl, -P (O) (O-C 1-4 alkyl) 2, C 1-6 alkylthio, C 1-6 alkylfinyl, C 1-6 alkyl sulfonyl, haloalkyl C1-6thio, haloalkyl C1-6sulfinyl, haloalkyl C1-6sulfonyl, oxyranyl, which in turn can be substituted with C1-6 alkyl and with a fused monocyclic or bicyclic ring system of five to ten members which can be aromatic partially saturated or completely saturated and may contain 1 to 4 heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, and where each ring system cannot contain more than 2 oxygen atoms and no more than 2 sulfur atoms, and where the ring system itself may be substituted with substituents selected from the group consisting of C1-6 alkyl, C1-6 haloalkyl, C1-6 alkoxy, C1-6 haloalkoxy, C1-6thio alkyl, C1-6 alkylfinyl, C1- alkyl 6sulfonyl, di (C1-4 alkyl) aminosulfonyl, di (C1-4 alkyl) amino, halogen, cyano, nitro and phenyl, and where the substituents on the nitrogen in the heterocyclic ring are different from halogen; or Y1 is a fused or monocyclic bicyclic ring system of five to ten members which may be aromatic, partially saturated or fully saturated and may contain 1 to 4 heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, where each ring system It cannot contain more than 2 oxygen atoms and no more than 2 sulfur atoms, and where the ring system itself can be substituted one to several times with substituents selected from the group consisting of C1-6 alkyl, C1- haloalkyl. 6, C1-6 alkoxy, C1-6 haloalkoxy, C1-6thio alkyl, C1-6sulfinyl alkyl, C1-6 alkyl sulfonyl, di (C1-4 alkyl) aminosulfonyl, di (C1-4 alkyl) amino, halogen, cyano, nitro and phenyl, and where the substituents on the nitrogen in the heterocyclic ring are different from halogen; or the group X1-Y1 together is formyl or cyano; each of R1a, R1b, R5a, R5b, R5c, R5d, R5e, R5f, R5g and R5h, which may be the same or different, represents hydrogen, halogen, nitro, cyano, hydroxy, CHO, C1-6 alkyl, alkenyl C2-6, C2-6 alkynyl. C3-6 cycloalkyl, C1-6 haloalkyl, C2-6 haloalkenyl, C2-6 haloalkynyl, C3-6 halocycloalkyl, C1-4 alkoxy, C1-4 alkoxy-C1-4 alkoxy-C1-4 alkyl, haloalkoxy C1-4, C1-4 alkylthio, haloC 1-4 alkylthio, haloC 1-4 alkyl sulfinyl, haloC 1-4 alkyl sulfonyl, C 1-4 alkyl sulfinyl, C 1-4 alkyl sulfonyl, C 1-4 alkyl sulfonyl C 1-4 alkyl, C 1-4 alkyl sulfoximino-C 1-4 alkyl, alkyl C1-4amino, C2-4amino dialkyl, C3-6amino cycloalkyl, C1-6alkylC3-6aminoalkyl, C2-4alkylcarbonyl, C2-6carbonyloxy, C2-6aminocarbonyl, C3-6aminocarbonyl dialkyl, C2-6carbonyloxy, C2-6alkyl 6-aminocarbonyloxy, C3-6 dialkylcarbonyloxy, C1-4 alkoxy-C1-4alkyl, C3-6silyl trialkyl, phenyl, benzyl or phenoxy; or represents phenyl, benzyl or phenoxy substituted once, twice or three times with substituents selected from the group consisting of halogen, cyano, nitro, halogen, C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, C3-6 cycloalkyl, haloalkyl C1-6, C2-6 haloalkenyl, C2-6 haloalkynyl, C3-6 halocycloalkyl, C1-4 alkoxy, C1-4 haloalkoxy, C1-4thio alkyl, C1-4thio haloalkyl, C1-4sulfinyl alkyl, C1-4sulfonyl alkyl, alkyl C1-4amino, C2-4amino dialkyl, C3-6amino cycloalkyl, C1-6alkylC3-6aminoalkyl, C2-4alkyl alkyl. C2-6 alkoxycarbonyl, C2-6 alkylaminocarbonyl, C3-6 dialkylcarbonyloxy, C2-6carbonyloxy alkoxy, C2-6aminocarbonyloxy, C3-6aminocarbonyloxy and C3-6 silyl trialkyl; each of R2 and R3, which may be the same or different, represents hydrogen, C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl or C3-8 cycloalkyl; or C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl or C3-8 cycloalkyl substituted once or several times with substituents selected from halogen, nitro, cyano, hydroxy, C1-4 alkoxy, C1-4 haloalkoxy, C1- alkyl 4thio, haloC 1-4 alkylthio, C 1-4 alkyl sulfinyl, C 1-4 alkyl sulfonyl, C 1-4 alkyl, C 1-4 dialkyl, C 3-6 cycloalkyl and C 1-6 alkylC 3-6 alkyl; D is 2-pyridyl, 3-pyridyl, 4-pyridyl; or phenyl, 2-pyridyl, 3-pyridyl or 4-pyridyl substituted once, twice or three times with C1-6 alkyl, C3-6 cycloalkyl, C1-6 haloalkyl, halogen, cyano, C1-4 alkoxy, C1-4 haloalkoxy , C1-4 alkylthio, C1-4 haloalkyl, C1-4 alkylfinyl, C1-4alkyl sulfonyl, haloC 1-4 alkyl sulfinyl or haloC 1-4 alkyl sulfonyl; or D is a remainder of the formula group (2); or D is phenyl; R4, R4 ', R10, R17 and R19 independently of each other, are hydrogen, C1-6 alkyl, C3-6 cycloalkyl, C1-6 haloalkyl, halogen, cyano, C1-4 alkoxy, C1-4 haloalkoxy, C2-4alkoxycarbonyl , C1-4 alkylthio, C1-4 haloalkyl, C1-4sulfinyl alkyl, C1-4sulfonyl alkyl, C1-4sulfinyl haloalkyl or C1-4sulfonyl alkyl; R5, R6, R8, R11, R12, R15, R16 and R18 independently of each other, are C1-6 alkyl, or C1-6 alkyl substituted once, twice or three times with halogen, cyano, nitro, hydroxy, C1-4 alkoxy , C 1-4 alkoxycarbonyl, C 1-4 alkylthio, C 1-4 alkyl sulfinyl, C 1-4 alkyl sulfonyl, C 1-4 alkyl, C 2-4 dialkyl or C 3-6 cycloalkyl; or are phenyl, 2-pyridyl, 3-pyridyl, 4-pyridyl; or are phenyl, 2-pyridyl. 3-pyridyl or 4-pyridyl substituted once, twice or three times with substituents selected from the group consisting of C1-6 alkyl, C3-6 cycloalkyl, C1-6 haloalkyl, halogen, cyano, C1-4 alkoxy, C1-4 haloalkoxy, C1-4 alkylthio, C1-4 haloalkyl, C1-4sulfinyl alkyl, C1-4sulfonyl alkyl, C1-4sulfinyl haloalkyl and C1-4sulfonyl alkyl; R7, R9, R13 and R14 independently of one another are hydrogen, C1-6 alkyl, C1-6 haloalkyl, C2-6 alkenyl, C2-6 haloalkenyl, C3-6 alkenyl or C3-6 haloalkenyl; R20 is hydrogen, C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, or C3-6 cycloalkyl or is C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl or C3-6 cycloalkyl substituted with one, two or three substituents selected from the group consisting of halogen, cyano, nitro, hydroxy, C1-4 alkyl, C1-4 alkoxy, C1-4 haloalkoxy, C1-4 alkyl, C1-4sulfinyl, C1-4sulfonyl alkyl, C1-4sulfoximino alkyl C2-6alkoxycarbonyl, C2-6alkylcarbonyl, C2-6silyl trialkyl, benzyl, phenoxy and a fused monocyclic or bicyclic ring system of three to ten members which can be aromatic, partially saturated or completely saturated, where the system of three to ten member rings may contain heteroatoms selected from the group consisting of oxygen, nitrogen and sulfur; where it is possible that said benzyl, phenoxy and fused monocyclic or bicyclic ring system of three to ten members, in turn, is substituted with one to three substituents independently selected from the group consisting of C1-4 alkyl, C2-4 alkenyl, alkynyl C2-4, C3-6 cycloalkyl, C1-4 haloalkyl, C2-4 haloalkenyl, C2-4 haloalkynyl, C3-6 halocycloalkyl, halogen, cyano, nitro, C1-4 alkoxy, C1-4 haloalkoxy, C1-4thio alkyl, C 1-4 alkyl sulfinyl, C 1-4 alkyl sulfonyl, C 1-4 alkyl sulfoximino, C 1-4 alkyl, C 1-6 alkyl dialino, C 3-6 cycloalkyl, C 1-4 alkylC 3-6 alkylamino, C 2-4 carbon alkyl, C 2-6 alkoxycarbonyl, C 2 alkyl -6-aminocarbonyl, C2-8 dialkylcarbonyl and C2-6silyl trialkyl; where it is possible that said fused monocyclic or bicyclic ring system, with three to ten members, is spiro-linked to the C3-6 cycloalkyl group; or R20 is C 1-4 alkoxy, C 1-4 alkyl, C 2-8 amino dialkyl, C 3-6 cycloalkyl, C 2-6 alkoxycarbonyl or C 2-6 alkylcarbonyl; or R20 is 3-oxetanyl, 3-thiethanyl, 1-oxo-3-thienyl, 1,1-dioxo-3-thienyl, 1-imino-1-oxo-3-thienyl or 3-azetidinyl; or R20 is 3-oxetanyl, 3-thiethanyl, 1-oxo-3-thienyl, 1,1-dioxo-3-thienyl, 1-imino-1-oxo-3-thienyl, 3-azetidinyl, each of which it is substituted once or several times with substituents independently selected from the group consisting of C1-4 alkyl, C1-4 haloalkyl, halogen, cyano, C6carbonyl alkoxy and C2-6carbonyl alkyl; each of Z1 and Z2, which may be the same or different, represents oxygen or sulfur; and salts, isomers, enantiomers, tautomers, N-oxides acceptable for agronomic use of those compounds. |
| priorityDate | 2007-08-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
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Total number of triples: 41.