http://rdf.ncbi.nlm.nih.gov/pubchem/patent/AR-050173-A1
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_981a37900e6991fb373304ed2ba5a703 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/A01N33-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/A01N33-16 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/A01N47-40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/A01N51-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/A01N33-22 |
| filingDate | 2005-07-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2006-10-04-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | AR-050173-A1 |
| titleOfInvention | INSECTICIDES BASED ON NEONICOTINOIDS AND PROTECTORS |
| abstract | Insecticidal compositions, which are used for the fight against arthropods, as well as procedures for the fight against arthropods by treating plants and their seeds with these compositions. Claim 1: Agents comprising an active content of a combination of active products, comprising: a) at least one compound of the formula (1), wherein Het means a heterocycle substituted respectively, on each die, once or several times by fluorine, by methyl or by ethyl, selected from the following groups of heterocycles: pyrid-3-yl, pyrid-5-yl, 3-pyridinium, 1-oxido-5-pyridinium, 1-oxido-5-pyridinium-tetrahydrofuran -3-yl, thiazol-5-yl; A means C1-6 alkyl, -N (R1) (R2) or S (R2), where R1 means hydrogen, C1-6 alkyl, phenyl-C1-4 alkyl, C3-6 cycloalkyl, C2-6 alkenyl or alkynyl C2-6; and R2 means C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, -C (= O) -CH3 or benzyl; R means hydrogen, C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, -C (= O) -CH3 or benzyl or together with R2 means one of the following groups: -CH2-CH2-, -CH2-CH2 -CH2-, -CH2-O-CH2-, -CH2-S-CH2-, -CH2-NH-CH2-, -CH2-N (CH3) -CH2-; and X means N-NO2, N-CN or CH-NO2, with the inclusion of all possible tautomeric forms of the compounds of the general formula (1) and salts or adducts with acids or bases, possible , of the compounds of the general formula (1); and b) at least one compatibility enhancing compound with the crop plants of the following group of compounds: 4-dichloroacetyl-1-oxa-4-aza-spiro [4.5] -decane (AD-67, MON-4660), - dichloroacetyl-hexahydro-3,3-8atrimethylpyrrolo [1,2-a] -pyrimidin-6 (2H) one (Dicyclonon, BAS-145138), 4-dichloroacetyl-3,4-dihydro-3- methyl-2H-1, 4-benzoxazine (Benoxacor), 5-chloro-quinolin-8-oxy-acetic acid (1-methyl-hexyl ester) (Cloquinotocet-mexyl- see also the products related in publications EP-A-86750, EP-A -94349, EP-A-191736, EP-A-492366, 3- (2-Chloro-benzyl) -1- (1-methyl-1-phenyl-ethyl) urea (Cumyluron), alpha- (cyanomethoximino) -phenylacetonitrile (Cyometrinyl), 2,4-dichloro-phenoxyacetic acid (2,4-D), 4- (2,4-dichloro-phenoxy) -butyric acid (2,4-DB), 1- (1-methyl-1 -phenyl-ethyl) 3- (4-methyl-phenyl) -urea (Daimuron, Dymron), 3,6-dichloro-2-methoxy-benzoic acid (Dicamba), S-1-methyl- piperidine-1-thiocarboxylate 1-phenyl-ethyl (Dimepiperate), 2,2-dichloro-N- (2-oxo-2- (2-propenylamino) -ethyl) -N- (2-propenyl) -acetamide (DKA-24), 2,2-dichloro-N, N-di-2-propenyl-acetamide (Dichlormid), 4,6-dichloro-2-phenyl-pyrimidin- ( Fenclorim), 1- (2,4-dichloro-phenyl) -5-trichloromethyl-1H-1,2,4-triazol-3-carboxylate (Fenclorazole-ethyl- see also the related compounds in EP-A publications -174562 and EP-A- 346620), phenylmethyl 2-chloro-4-trifluoromethyl-thiazol-5-carboxylate (Flurazole), 4-chloro-N- (1,3-dioxolan-2-yl-methoxy) -alpha -trifluor-acetophenonoxime (Fluxofenim), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyl-oxazolidine (Furilazole, MON-13900), 4,5-dihydro-5,5-diphenyl-3-isoxazolcarboxylate of ethyl (Isoxadifen-ethyl- see also the compounds related in publications WO-A-95/07897), 1- (ethoxycarbonyl) -ethyl-3,6-dichloro-2-methoxybenzoate (Lactidichlor), acid (4-chloro -o-tolyloxy) a-acetic acid (MCPA), 2- (4-chloro-o-tolyloxy) -propionic acid (Mecoprop), 1- (2,4-dichloro-phenyl) -4,5-dihydro-5- methyl-1H-pyrazol-3,5-diethyl dicarboxylate (mefenpyr-diethyl- see also in the compounds related to WO-A-91/07874) 2- dichloromethyl-2-methyl-1,3-dioxolan (MG-191), 2-propenyl-1-oxa-4-azaspiro [4.5] decane- 4-carbodithioate (MG-838), 1,8-naphthalic acid anhydride, alpha- (1,3-dioxolan-2-yl-methoximino) -phenylacetonitrile (Oxabetrinyl), 2,2-dichloro-N- (1, 3-dioxolan-2-yl-methyl) -N- (2-propenyl) acetamide (PPG-1292), 3-dichloroacetyl-2,2-dimethyl-oxazolidine (R-28725), 3-dichloroacetyl-2,2, 5-Trimethyl-oxazolidine (R-29148), 4- (4-chloro-o-tolyl) -butyric acid, 4- (4-chloro-phenoxy) -butyric acid, diphenylmethoxyacetic acid, methyl diphenylmethoxyacetate, methyl diphenylmethoxyacetate, Methyl 1- (2-Chloro-phenyl) -5-phenyl-1H-pyrazol-3-carboxylate, 1- (2,4-dichloro-phenyl) -5-methyl-1H-pyrazol-3-carboxylate, Ethyl 1- (2,4-dichloro-phenyl) -5-isopropyl-1H-pyrazol-3-carboxylate, 1- (2,4-dichloro-phenyl) -5- (1,1-dimethyl-ethyl) - Ethyl 1H-pyrazol-3-carboxylate, 1- (2,4-dichloro-phenyl) -5-phenyl-1H-pyrazol-3-carboxylate ethyl (see also compose These are related in EP-A-269806 and EP-A-333131), 5- (2,4-dichloro-benzyl) -2-ethyl isoxazolin-3-carboxylate, 5-phenyl-2-isoxazolin-3- ethyl carboxylate, 5- (4-fluorophenyl) -5-phenyl-2-isoxazolin-3-carboxylate (see also the compounds related in WO-A-91/08202), 5- chloro-quinolin -8-Oxy-acetic-ester of (1,3-dimethyl-but-1-yl), 5-chloro-quinolin-8-oxy-acetate of 4-allyloxy-butyl, 5-chloro-quinolin-8-oxy - 1-Allyloxy-prop-2-yl acetate, 5-chloro-quinoxalin-8-oxy-methyl acetate, 5-chloro-quinolin-8-oxy-ethyl acetate, 5-chloro-quinoxalin-8-oxy allyl acetate, 5-chloro-quinolin-8-oxy-2-oxo-prop-1-yl acetate, diethyl 5-chloro-quinolin-8-oxy-malonate, 5-chloro-quinoxalin-8-oxy diallylmalonate, 5-chloro-quinolin-8-oxy-diethyl malonate (see also the compounds related in EP-A-582198), 4-carboxy-chroman-4-yl-acetic acid (AC-304415 , see EP-A-613618), 4-chloro-phenoxy-acetic acid, 3 , 3'-dimethyl-4-methoxy-benzophenone, 1-bromo-4-chloromethylsulfonolbenzene, 1- [4- (N-2-methoxybenzoylsulfamoyl) -phenyl] -3-methyl-urea (alias N- (2- methoxy-benzoyl) -4 - [(methylamino) -amino] -benzenesulfonamide), 1- [4- (N-2-methoxybenzoylsulfamoyl) -phenyl] -3,3-dimethyl-urea, 1- [4- (N- 4,5-dimethylbenzoylsulfamoyl) -phenyl] -3-methyl-urea, 1- [4- (N-naphthylsulfamoyl) -phenyl] -3,3-dimethyl-urea, N- (2-methoxy-5-methyl-benzoyl) ) -4- (cyclopropylaminocarbonyl) -benzenesulfonamide; one of the following compounds, defined by general formulas, of the formula (2), or of the general formula (3), or of the formula (4), in which: m means a number between 0 and 5; A1 means one of the divalent heterocyclic clusters schematized in the group of formulas (5); n means a number between 0 and 5; A2 means alkanediyl with 1 or 2 carbon atoms substituted, where appropriate, by C1-4 alkyl, by C1-4 alkoxycarbonyl and / or by C1-4 alkenyloxycarbonyl; R8 means hydroxy, mercapto, amino, C1-6 alkoxy, C1-6 alkylthio, C1-6 alkylamino or di- (C1-4 alkyl) -amino; R9 means hydroxy, mercapto, amino, C 1-7 alkoxy, C 1-6 alkenyloxy, C 1-6 alkenyloxy, C 1-6 alkyloxy, C 1-6 alkylthio, C 1-6 alkylamino or di- (C 1-4 alkyl) -amino; R10 means C1-4alkyl respectively substituted, if appropriate, by fluorine, by chlorine and / or by bromine; R 11 means hydrogen, C 1-6 alkyl, C 2-6 alkenyl or C 2-6 alkynyl, C 1-4 alkoxy, C 1-4 alkyl, dioxolanyl C 1-4 alkyl, furyl, C 1-4 alkyl furyl, thienyl, thiazolyl, piperidinyl, respectively, where appropriate, by fluorine, by chlorine and / or bromine, or means phenyl substituted, where appropriate, by fluorine, by chlorine and / or by bromine or by C1-4 alkyl; R 12 means hydrogen, C 1-6 alkyl, C 2-6 alkenyl or C 2-6 alkynyl, C 1-4 alkoxy, C 1-4 alkyloxylaryl-C 1-4 alkyl, furyl C 1-4 alkyl, thienyl, thiazolyl, piperidinyl, respectively, in case given, by fluorine, by chlorine and / or by bromine, or substituted phenyl, if appropriate, by fluorine, by chlorine and / or by bromine or by C1-4alkyl, and R11 and R12 also means, together, C3- alkanediyl 6 or C2-5 oxaalkanediyl substituted, if appropriate, by C1-4 alkyl, by phenyl, by furyl, by an over-ringed benzene ring or by two substituents that form, together with the carbon atom, with which they are linked, a carboxycycle with 5 or 6 members; R13 means hydrogen, cyano, halogen, or means C1-4 alkyl, C3-6 cycloalkyl or phenyl substituted respectively, where appropriate, by fluorine, by chlorine and / or by bromine; R 14 means hydrogen, C 1-6 alkyl, C 3-6 cycloalkyl or tri-C 1-4 alkyl-silyl substituted, if appropriate, by hydroxy, by cyano, by halogen or by C 1-4 alkoxy; R15 means hydrogen, cyano, halogen, or means C1-4 alkyl, C3-6 cycloalkyl or phenyl substituted respectively, where appropriate, by fluorine, by chlorine and / or by bromine; X1 means nitro, cyano, halogen, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy or C1-4 halogenoalkoxy; X2 means hydrogen, cyano, nitro, halogen, C1-4 alkyl, C1-4 halogenoalkyl, C1-4 alkoxy or C1-4 halogenoalkoxy; X3 means hydrogen, cyano, nitro, halogen, C1-4 alkyl, C1-4 halogenoalkyl, C1-4 alkoxy or C1-4 halogenoalkoxy; and / or the compounds defined below by means of the general formulas of the general formula (6), or of the general formula (7), in which: r and s mean a number between 0 and 5; R16 means hydrogen, or C1-4 alkyl; R17 means or C1-4 alkyl; R18 means hydrogen, C1-6 alkyl, C1-6 alkoxy, C1-6 alkylthio, C1-6 alkylamino or di-C1-4alkyl substituted respectively, if appropriate, by cyano, by halogen or by C1-4 alkoxy, or means C3-6 cycloalkyl, C3-6 cycloalkyloxy, C3-6 cycloalkylthio or C3-6 cycloalkylamino substituted respectively, if appropriate, by cyano, by halogen or by C1-4 alkyl; R19 means hydrogen, C1-6 alkyl substituted, if appropriate, by cyano, hydroxy, halogen or C1-4 alkoxy, means C3-6 alkenyl or C3-6 alkynyl substituted respectively, on each die, by cyano or by halogen, or means C3-6 cycloalkyl substituted, if appropriate, by cyano, by halogen or by C1-4 alkyl; R20 means hydrogen, C1-6 alkyl substituted, if appropriate, by cyano, hydroxy, halogen or C1-4 alkoxy, means C3-6 alkenyl or C3-6 alkynyl substituted respectively, on each die, by cyano or by halogen, means C3-6 cycloalkyl substituted, if appropriate, by cyano, by halogen or by C1-4 alkyl, or means substituted phenyl, if necessary, by nitro, by cyano, by halogen, by alky |
| priorityDate | 2004-07-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
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Total number of triples: 131.