http://rdf.ncbi.nlm.nih.gov/pubchem/patent/AR-030009-A1
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_d225eacc0d6d94f83eeeaaba9abc4f21 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/A01N33-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/A01N43-40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-70 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/A01N31-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-64 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C323-58 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C323-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C259-06 |
| filingDate | 1999-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2003-08-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | AR-030009-A1 |
| titleOfInvention | ETERES OF VINYLLARILY OF HERBICIDE PROPERTIES, COMPOSITIONS AND PRODUCTS FORMULATED WITH SUCH COMPOUNDS; METHODS TO CONTROL WEEDS IN A PLACE BY APPLYING SUCH COMPOSITIONS; METHODS TO REDUCE THE PHYTO-TOXICITY OF SUCH COMPOUNDS ON GRAMINES AND PROCESSES TO PREPARE COMPOUNDS |
| abstract | These are arylvinyl ethers of general formula (1), where p is 0 or 1, X1 is O, NH or S; X2 is O, S, NR18 or n single bond; X3 is N or CR19; R17 and R18 independently represent an hydrogen atom or an optionally substituted R20, R21, R22 or R23 group, in which: R20 represents a lower alkyl radical; R21 represents a lower alkenyl radical; R22 represents a lower alkynyl radical; R23 represents a radical û (CH2) m-phenyl; m represents zero or one; R16 is R24 or OR25 or SR25R26 or alkyl substituted with alkoxycarbonyl; R24, R25 and R26 independently have one of the meanings given for R18; R19 has one of the meanings given for R16; R10 represents a radical selected from: CH2NO2, -CHR27R28, -CR27R28R28 ', -CR30R29R29', -CO-NR30R31, -CH2NR30R31, -CH = CR31R32, -CH2N (R30) S (O) qR33, -C (O) SR32 , -CH2C (O) SR32, - (CH2) zCO2R32, -CO2R32, -CH = CHC (O) OR32, -C (R32) = N-NR30R31, -C (R32) = N-NH-C (O) -lower alkyl, -COR32, -C (O) OC (O) R32, -C (= N-OH) R32, -CsCCOOR32, -CH2SCN, -CH2NCO, -CH2NCS, -CH2N3, -CH2CN, -CH2OSCN, CH2OCN , -CH2N (R30) CO2R33, -CH2OSO2R33, -CH2SO2OR33, CH2OCO2R33, -CH = CHNR33R34, -C (O) ONR33R34, -C (= NR35) R32, -CH2P (O) R35R36, -CH2OP (O) R35R36, -CH2OC (O) NR30R36, -CH2OCH2C (O) - (optionally substituted phenyl), -CO2N = C- (optionally substituted phenyl) 2, N-succinimidomethyl, N-phthalimidomethyl, a tetrazolyl group (especially 1-tetrazolyl), - CONHNHR30, -CO2CH2CO- (optionally substituted phenyl, or a saturated or unsaturated 5-7 membered heterocyclic ring containing 1-3 heteroatoms selected from O, N and S), -CO2CH2- (saturated or unsaturated 5- heterocyclic ring 7 members containing 1-3 heteroatoms selected from O, N and S), CO2R32a, COCH2COR33, COCHN2, CONH- (lower alkyl substituted with hydroxyl), -CH (O) - (lower alkyl), C (R32) = N-NH-C (S) NRa , C (R32) = N-NH- (optionally substituted 5-7 membered unsaturated heterocyclic ring containing 1-3 atoms selected from O, N and S), C (R32) = N-NR30aR31a, C (R32) = N-NHSO2R33 and C (O) F; z represents one, two, three or four; q represents zero or two; Ra represents H or lower alkyl; R32a represents an optionally substituted N-linked imidazole, or an optionally fused triazole ring with a benzene ring; R30a and R31a, together with the N atom to which they are attached, form a saturated 5- or 6-membered heterocyclic ring, optionally containing an additional O, S or NRa group in the ring; R27, R28 and R281 represent the same or different halogen atoms; R29 and R291 represent OR37 or SR37 or, R29 and R291 together form a divalent radical, with which the carbon atom to which they are attached forms a 5- to 6-membered cyclic acetal or thioacetal ring, whose ring system is optionally substituted with one or more lower alkyl groups; R30, R31 and R32 independently represent hydrogen, lower alkyl, lower haloalkyl, lower alkoxyalkyl, lower alkenyl, lower haloalkenyl, lower alkynyl, lower haloalkynyl, optionally substituted cycloalkyl, - (CH2) m-phenyl optionally substituted; R33 and R34 represent R32 with the exclusion of the hydrogen atom; R35 and R36 represent a hydrogen atom or a radical which can be any of the following: optionally substituted alkyl, alkoxy or phenyl; R37 represents lower alkyl, lower haloalkyl, lower alkenyl or lower haloalkenyl; R11 and R13 each independently represent hydrogen or alkyl, or R11 and R13 can be together a single bond that creates a double bond with the carbon atom to which they are attached, or R11 and R13 can be a single, divalent radical comprising one or six atoms in the main chain, this main chain optionally containing one to three nitrogen atoms, an oxygen atom or a sulfur atom; forming this divalent radical, with the two carbon atoms to which it is attached, a saturated or unsaturated carbocyclic or heterocyclic ring or a bicyclic ring, these rings being optionally substituted with one to four R15 radicals, each ring containing a maximum of eight members per ring, preferably at most six, in which R15 represents a halogen, hydroxy, cyano, lower alkoxycarbonyl, lower alkyl, lower alkenyl, alkynyl, lower, optionally substituted cycloalkyl, lower alkoxy, lower alkylthio, lower alkylsulfinyl, lower alkylsulfonyl atom , lower haloalkoxycarbonyl, lower haloalkyl, lower haloalkenyl, lower haloalkynyl, halocycloalkyl, lower haloalkoxy, lower haloalkylthio, lower haloalkylsulfinyl, lower haloalkylsulfonyl, nitro, amino, lower alkylamino, lower dialkylamino, optionally substituted phenyl, lower alkylcarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylaminocarbonylamino lower oyl, lower dialkylcarbamoyl, -CH2SCN, SF5, -CR30 = N-R31, -CR30 = NOR31, -CR30 = NNR30R31, -CR30R29R291, alkoxyalkyl, CRbRcRa, CORa, phenyl, or naphthyl optionally substituted; or alkenyloxy substituted with alkoxycarbonyl or CO2H; Rb and Rc, together with the C atoms to which they are attached, form a 5- or 6-membered cyclic acetal group; or R10R11R12C-C (R13) (R14) û represents a group (A), (B), (C), (D) or (E): in which Rd, Re, Rf, Rg and Rh represent H, alkyl lower, halogen or OH, and n represents the values of 0, 1, 2, or 3; R151 represents R15 or a hydrogen atom; R12 and R14 each independently represent hydrogen or alkyl, or they can form a single bond, creating a double bond together when R11 and R13 are, together, a single bivalent radical; preferably with the following conditions: i) when R10R11R12C-C (R13) (R14) - represents a phenyl ring optionally substituted with R15, R10 represents ûCO2R32, CONR30R11, CHR27R28 or CR27R28R281, in which R32 represents alkyl or haloalkyl; R30 and R31 represent H or alkyl, and R27, R28 and R281 are as defined above; p is zero; X1 is O; X2 is O; X3 is CH; R16 is OR25; then R15 is not a monohalomethyl group; ii) when R10R11R12C-C (R13) (R14) - represents an EtO2C-CH = CH- group; p is 1; X1 is S; X2 is a link; r17 represents phenyl; X3 is CH; then R16 is not nH2 or Nme2; iii) when R11, R12, R13, R14 each represents H; p is 1; X1 is S; X2 is O; R17 represents Et, X3 is N; R16 represents ûNH (4-nitrophenyl); R10 is not CO2H or CONHPh; iv) when R11, R12, R13, R14 each represents H; p is zero; X1 is S; X2 is O; R17 represents Et; X3 is N; R16 represents ûNH (4-nitrophenyl); R10 is not CO2H or CONH2; v) when p represents zero; X1 is O; X2 is a link; R17 represents H; X3 is CH; R16 represents Nme2; R10R11R12C-C (R13) (R14) - represents a substituted 5-methyl-2-R10-thien-3-yl group; R10 is not CO2H or CO2Me; vi) when R11, R12, R13 and R14 each represents H; p is zero; X1 is S; X2 is O; R17 represents H; X3 is N; R16 represents ûNH (4nitrophenyl); R10 is not CO2H; vii) when R10 represents CO2Et; R11, R12, R13, R14 each represents H; p is zero; X1 is S; X2 is NH; R17 represents phenyl; X3 is CMe; R16 is not NH2 or NHMe; and viii) when p is zero; X1 is O; X2 is O; R17 represents Me; X3 is CH, R16 represents OMe; R10R11R12C-C (R13) (R14) - represents a 1,3-dimethyl-4-R10-pyrazol-5-yl-substituted group; R10 is not 4-chlorobenzoyl; and agriculturally acceptable metal salts and complexes thereof. The objects provided in the title are also prepared. |
| priorityDate | 1998-07-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
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Total number of triples: 33.