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filingDate 1999-05-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2001-07-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber AR-016469-A1
titleOfInvention COMPOSITION CAPABLE OF FORMING A POLYMERIC EMULSION STABILIZED WITH ALMIDON, POLYMERIC EMULSION STABILIZED WITH ALMIDON, METHOD FOR FORMING LAEMULSION AND COATING AND INK COMPOSITION THAT INCLUDE THE EMULSION
abstract Composition capable of forming a starch stabilized polymer emulsion, starch stabilized polymer emulsion, method for forming the emulsion and coating and ink composition comprising the emulsion. The composition capable of forming a starch stabilized polymer emulsion comprises approximately 5% to 30% by weight of total solids of an undegraded starch; about 1% to 5% by weight of total solids of a perulfate salt; and at least about 70% total solid weight of an ethylenically unsaturated monomer. The composition is essentially free of iron, preferably it is essentially free of iron, nickel, manganese, cerium and copper. Which is highly convenient in particular applications, since their presence tends to discolor the resulting products. This is a particular problem for products used in the graphic arts and coatings industries for products such as detinta binders and coatings binders. However, it is noted that such metals are typically used in starch graft emulsion copolymer systems, either to degrade elalmidon or to facilitate polymerization. The method of forming a stabilized polymeric starch emulsion allows the starch to be degraded by the persulfate salt; and while at least a portion of said starch is still being degraded by the persulfate salt, the addition of degradation starch monomers causes the degradation starch to be graft copolymerized with the monomers. The formation of said emulsions uses persulfate desalts to essentially simultaneously degrade the starch and initiate polymerization, as opposed to non-simultaneous degradation and graft polymerization processing, where a set of conditions are often specified for starch degradation (for example , to modify its viscosity and other characteristics), and another set of conditions is then used for graft polymerization. Changing the
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